Toxic Pollution and Health in US Communities, US PIRG, 2007
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An Analysis of Toxic Chemicals Released in Communities across the United States U.S. PIRG Education Fund March 2007 TOXIC POLLUTION AND HEALTH An Analysis of Toxic Chemicals Released in Communities across the United States U.S. PIRG Education Fund March 2007 ACKNOWLEDGMENTS Written by Alison Cassady and Alex Fidis of the U.S. PIRG Education Fund. © 2007, U.S. PIRG Education Fund Cover photos: Photodisc (water pollution); invictus99/FOTOLIA (smokestack); and Jason Smith/FOTOLIA (toxic waste drums). The authors would like to thank Tom Natan of National Environmental Trust and Sean Moulton of OMB Watch for their input on this report. We also thank Tony Dutzik, Policy Analyst with the Frontier Group, who wrote an earlier version of this report from which we draw extensively. Special thanks to the Bauman Foundation and Beldon Fund for their financial support of U.S. PIRG Education Fund’s work on toxics and environmental health issues. The authors alone are responsible for any factual errors. The recommendations are those of the U.S. PIRG Education Fund. The views expressed in this report are those of the authors and do not necessarily reflect the views of our funders or those who provided editorial review. For additional copies of this report, send $20 (including shipping) to: U.S. PIRG Education Fund 218 D St. SE Washington, DC 20003 202-546-9707 www.uspirg.org U.S. PIRG is the federation of state Public Interest Research Groups (PIRGs). The state PIRGs are independent, state-based, citizen-funded organizations that advocate for a healthy environment, a fair and sustainable economy, and a responsive democratic government. 2 TABLE OF CONTENTS Executive Summary ................................................................................................................... 4 Introduction ............................................................................................................................... 6 Toxic Releases in the United States ........................................................................................... 7 Toxic Releases to Air and Water.............................................................................................................. 7 Carcinogens............................................................................................................................................... 7 Developmental and Reproductive Toxicants ....................................................................................... 10 Suspected Neurotoxicants .....................................................................................................................15 Suspected Respiratory Toxicants ..........................................................................................................19 Dioxins .....................................................................................................................................................21 Toxic Releases to Land..............................................................................................................................24 Bush Administration Weakens the Toxics Release Inventory.................................................. 27 Background: TRI Reporting Requirements ...........................................................................................27 Bush Administration Weakens Toxic Release Reporting Requirements ...........................................28 Recommendations ................................................................................................................... 30 Methodology ........................................................................................................................... 33 Appendices.............................................................................................................................. 34 End notes ................................................................................................................................. 63 3 EXECUTIVE SUMMARY I ndustries across the United States pump billions of pounds of toxic chemicals into our air, land, and water each year, many of which can cause cancer and other severe health effects. The Environmental Protection Agency’s Toxics Release Inventory (TRI) program provides Americans with the best information about toxic chemicals released in their communities. Unfortunately, in December 2006 the Bush administration limited the public’s right-to-know about this pollution by giving some polluters a free pass on reporting their toxic emissions. The TRI program is a critical tool for citizens, public health officials, and policy-makers interested in identifying trends in toxic pollution at the local, state and national levels. Each year, the country’s largest facilities from a range of industries report their air, water, and land releases of more than 600 toxic chemicals, providing valuable information about which chemicals are entering the environment and where. For some of these chemicals, scientists know little about their effects on public health and the environment. For many, however, scientists have linked exposure to harmful health effects ranging from chronic bronchitis to developmental problems to cancer. Using the latest available TRI data, we examined releases of chemicals known or suspected to cause serious health problems and identified states and localities that are bearing the brunt of this pollution. Specifically, we looked at releases of substances recognized by the state of California to cause cancer, birth defects or reproductive problems; we also looked at releases of substances suspected by scientists to damage the neurological or respiratory systems. Our findings include: Industries continue to release toxic chemicals linked to severe health effects into our air and water. In 2004, U.S. facilities—led by the chemical and paper industries—released more than 70 million pounds of recognized carcinogens to the air and water. Texas, South Carolina, Louisiana, Alabama and Florida ranked highest for air and water releases of carcinogens. In 2004, U.S. facilities—led by the chemical industry—reported more than 96 million pounds of air and water emissions of chemicals linked to developmental problems, such as birth defects and learning disabilities, and almost 38 million pounds of chemicals linked to reproductive disorders. Tennessee ranked first in overall releases of both developmental and reproductive toxicants, followed by Texas and Illinois. In 2004, U.S. facilities—led by the chemical and paper industries and electric utilities—released more than 826 million pounds of suspected neurological toxicants to the air and water. Texas, Tennessee, Georgia, Louisiana, and Ohio ranked highest for air and water releases of neurotoxicants. In 2004, U.S. facilities released almost 1.5 billion pounds of suspected respiratory toxicants to the air, with electric utilities accounting for almost half of the pollution. Ohio, North Carolina, Tennessee, Texas and Pennsylvania ranked highest for respiratory toxicant releases to air. In 2004, U.S. facilities reported releasing 2,631 grams of dioxins—one of the most dangerous substances known to science— to the air and water. The chemical industry and electric utilities released the most dioxins. 4 A relatively small number of communities often experience the bulk of the air and water pollution. In 2004, almost a quarter (24 percent) of all air and water releases of carcinogens occurred within just 20 U.S. counties. Four Texas counties—Harris, Galveston, Brazoria, and Jefferson— ranked in the top five counties for most carcinogenic emissions. Tennessee, Texas and Illinois accounted for more than 40 percent of the nation’s developmental toxicant releases and more than 70 percent of the reproductive toxicant releases in 2004. Almost two-thirds (62 percent) of all air and water releases of dioxins reported to TRI in 2004 occurred within just 20 zip codes. Zip code 77541 in Freeport, Texas and 70765 in Plaquemine, Louisiana are home to the two facilities— both owned by Dow Chemical—that released the most dioxins in 2004. The mining industry overwhelmingly releases the most toxic pollution to land. In 2004, U.S. facilities reporting to TRI released more than 608 million pounds of carcinogens, developmental toxicants and reproductive toxicants to land. The metal mining industry was responsible for about 485 million pounds (80 percent) of these releases. Two-thirds (67 percent) of the land releases of carcinogens, developmental toxicants and reproductive toxicants were lead or lead compounds. Exposure to lead can affect almost every organ and system in the human body, especially the central nervous system. Nevada, Alaska, and Utah ranked highest for land releases of carcinogens, developmental toxicants and reproductive toxicants in 2004, accounting for 71 percent of the land releases of these substances nationally. The Bush administration has limited the public’s right-to-know about toxic releases. On December 22, 2006, the Bush administration finalized a new rule that will reduce the quantity and quality of toxic chemical data submitted under TRI and available to the public. Specifically, the new rule allows facilities to avoid submitting detailed reports for management of persistent bioaccumulative toxins (other than dioxins) under 500 pounds. These substances persist in the environment, and even minute amounts pose a serious risk to public health. For all other chemicals, the Bush administration raised the threshold at which companies are required to submit detailed reports from 500 pounds to 5,000 pounds per year of waste generation, if not more than 2,000 pounds are released to the environment. The end result is that the public will have less information about toxic pollution released in communities. The public needs more information about toxic pollution, not less, and facilities need to cut toxic chemical use and releases. The Bush administration should reverse its policy that limits reporting of toxic chemicals and instead strengthen the quality and quantity of data provided to the public. Moreover, the United States needs to make toxics use reduction a priority and require facilities to find safer alternatives to dangerous chemicals. 5 INTRODUCTION E very day in America, industrial facilities release millions of pounds of toxic substances into the nation’s air and water. Many Americans – especially those who live in close proximity to industrial facilities – harbor deep concern about how those toxic releases may affect their health. Congress established the Toxics Release Inventory (TRI) program in 1986 as a part of the Emergency Planning and Community Right-to-Know Act (EPCRA). According to the Conference Report from the passage of EPCRA, Congress intended to “provide the public with important information on hazardous chemicals in their communities.”1 Under EPCRA, industrial facilities in specific sectors must disclose to the Environmental Protection Agency (EPA) their releases of approximately 650 toxic chemicals to air, water, and land, as well as the quantities of chemicals they recycle, treat, burn, or otherwise dispose of on-site and off-site. The primary purpose of the TRI program is to inform citizens, emergency responders, and local and state governments of toxic hazards in communities.2 By providing information on toxic chemical releases, the TRI program empowers citizens and local governments to hold companies accountable for how toxic chemicals are used and managed in their communities. The TRI program has some limitations. Not all industries and facilities have to report their toxic pollution, and those that do report do not have to disclose releases of all chemicals. That said, the TRI program remains a critical tool for citizens and others who are concerned about toxic chemicals released, burned, and otherwise present in their communities. Unfortunately, as described later in this report, the Bush administration finalized a rule in December 2006 that will enable facilities to withhold currently reported toxic chemical information from the public. This report uses the most recent TRI data available to show which industries are releasing carcinogens and other harmful substances, where, and in what amounts. In doing so, this report also demonstrates something else: the importance of the TRI program for understanding the problem of toxic chemicals in our communities. 6 TOXIC RELEASES IN THE UNITED STATES I ndustries across the United States continue to pump billions of pounds of toxic chemicals into our air, land, and water. For some of these chemicals, scientists know little about their potential effects on public health and the environment. In the most recent government study on the subject, EPA found in 1998 that it had the full set of basic toxicity information for only seven percent of the high volume chemicals manufactured in the United States.3 For many chemicals, however, scientists have linked exposure to harmful health effects ranging from chronic bronchitis to developmental problems to cancer. Using the most recent data from the Toxics Release Inventory, we examined which industries are releasing chemicals known or suspected to cause serious health problems and which communities are bearing the brunt of this pollution. Specifically, we looked at: maintains the most comprehensive list available of chemicals known to cause cancer, birth defects or other reproductive problems as part of Proposition 65, an initiative passed by voters in 1986 to inform Californians about their exposure to toxic chemicals. Releases of suspected neurotoxicants and respiratory toxicants. No government agency maintains an authoritative list of toxic chemicals that are known to cause neurological or respiratory problems. Environmental Defense, however, has compiled a comprehensive list of substances suspected by government or academic researchers to damage the neurological and respiratory systems. Communities would not know about these toxic chemical releases without the Toxics Release Inventory program, unless facilities opted to voluntarily disclose this information. Releases of known carcinogens and chemicals known to cause developmental and reproductive problems. California TOXIC RELEASES TO AIR AND WATER Industries reporting to the Toxics Release Inventory released 1.8 billion pounds of toxic pollution to our air and water in 2004.4 Scientists have linked exposure to many of these toxic chemicals to severe health effects, including cancer; many more remain understudied and their health effects poorly understood. Since not all industries and facilities report to TRI and those that do report do not have to disclose releases of all chemicals, the following likely understates the problem of toxic pollution in the United States. CARCINOGENS A carcinogen is a substance that causes cancer, including malignant tumors and other cancerous diseases such as leukemia. The risk of cancer accumulates over a lifetime. In 7 the United States, men have about a 1 in 2 lifetime risk of developing cancer; for women, the lifetime risk is slightly more than 1 in 3.5 Scientists estimate that exposure to carcinogens in the workplace or the general environment account for at least six percent of cancer deaths, or 33,900 people each year.6 Scientists know a great deal about cancer risks from exposure to some substances. Studies have shown that workers exposed to asbestos, for example, have a greater risk of developing lung cancer and malignant mesothelioma.7 Similarly, many studies have shown that radon, which develops from the decay of naturally-occurring uranium in soil and rock and can accumulate in basements and underground unventilated spaces, can cause lung cancer.8 Based on extensive scientific research, the state of California has listed almost 500 substances as known to cause cancer under Proposition 65. The TRI program does not require industries to report their releases of all of these substances. FINDINGS In 2004, U.S. facilities reporting to TRI released more than 70 million pounds of recognized carcinogens directly to the air and water. Acetaldehyde was the most frequently released carcinogen, with total air and water releases of almost 14 million pounds (Table 1). Acetaldehyde is used primarily as a chemical intermediate, principally for the production of certain acids and other chemicals. Human exposure occurs most often through inhalation, especially in urban areas or near other sources of combustion.9 Studies have linked inhalation exposure to acetaldehyde with an increased incidence of respiratory tract tumors in laboratory animals.10 In addition to being listed as a known carcinogen under Proposition 65, acetaldehyde is a suspected respiratory and neurological toxicant. Table 1. Carcinogens Released in the Highest Volume to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 Chemical ACETALDEHYDE FORMALDEHYDE DICHLOROMETHANE BENZENE TRICHLOROETHYLENE Total Air and Water Emissions 13,866,013 13,006,975 6,749,078 6,666,412 6,150,291 The chemical industry was responsible for 17.3 million pounds (25 percent) of all releases of carcinogenic substances to the air and water in the United States during 2004, followed by the paper industry, lumber and wood products industry, and petroleum refineries (Table 2). BP’s Texas City refinery, one of the largest refineries in the country, topped the list for the most releases of recognized carcinogens to the air and water, including more than 1.9 million pounds of formaldehyde. Similarly, the 3V chemical facility in Georgetown, South Carolina released almost 861,000 pounds of dichloromethane and 23,000 pounds of acetaldehyde into the air and water (Table 3). Table 2. Industries Releasing the Most Carcinogens to Air and Water, 2004 (pounds) Rank 1 2 3 4 Industry Chemicals and Allied Products Paper and Allied Products Lumber and Wood Products, Except Furniture Petroleum Refining and Related Industries Total Air and Water Emissions 17,320,073 12,409,815 6,085,273 5,331,550 5 6 7 8 9 10 Fabricated Metal Products, Except Machinery and Transportation Equipment Primary Metal Industries Food and Kindred Products Transportation Equipment Stone, Clay, Glass, and Concrete Products Rubber and Miscellaneous Plastics Products 4,097,416 4,096,199 3,507,874 3,300,501 2,832,873 2,739,830 8 Table 3. Facilities Releasing the Most Carcinogens to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Facility BP TEXAS CITY REFINERY 3V INC UNITED STATES SUGAR CORP WEYERHAEUSER CO EASTMAN KODAK CO. DDE LOUISVILLE U.S. AIR FORCE DYESS AFB GE PLASTICS TRIGEN-BOSTON ENERGY PLUM CREEK MDF INC City TEXAS CITY GEORGETOWN BRYANT LONGVIEW ROCHESTER LOUISVILLE DYESS AFB MOUNT VERNON BOSTON COLUMBIA FALLS State TX SC FL WA NY KY TX IN MA MT Total Air and Water Emissions 2,086,948 883,714 726,120 697,693 620,628 538,858 524,899 524,305 478,090 473,295 The Southeastern and Gulf regions of the country experienced the most carcinogenic pollution, with Texas, South Carolina, Louisiana, Alabama and Florida ranking highest for total carcinogen releases to air and water in 2004 (Figure A). These states are home to more than 300 chemical facilities, 40 pulp, paper and paperboard mills, and 90 petroleum refining facilities that reported emissions of carcinogens in 2004. See Appendix A for a list of all states with facilities releasing carcinogens to air and water in 2004. Figure A. Air and Water Releases of Carcinogens by State, 2004 (pounds) Note: Hawaii reported 93,000 pounds of carcinogens released to air and water in 2004; Alaska reported 48,000 pounds. 9 In 2004, almost one-fifth (18 percent) of all air and water releases of carcinogens reported to TRI occurred within just 20 zip codes. Zip code 77590 in Texas City, Texas, the site of several chemical facilities and refineries, ranked first for total releases of carcinogens to air and water, followed by zip code 29440 in Georgetown, South Carolina and 98632 in Longview, Washington (Table 4). Similarly, almost a quarter (24 percent) of all air and water releases of carcinogens reported to TRI occurred within just 20 U.S. counties. Four Texas counties—Harris, Galveston, Brazoria, and Jefferson—ranked in the top five counties for most carcinogenic air and water emissions in 2004 (Table 5). See Appendix B for the 100 U.S. zip codes and Appendix C for the 100 U.S. counties reporting the most carcinogens released to air and water in 2004. Table 4. Top 10 U.S. Zip Codes for Air and Water Releases of Carcinogens, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Zip Code 77590 29440 98632 33439 40216 35601 14652 77530 47620 79607 City TEXAS CITY GEORGETOWN LONGVIEW BRYANT LOUISVILLE DECATUR ROCHESTER CHANNELVIEW MOUNT VERNON DYESS AFB State TX SC WA FL KY AL NY TX IN TX Total Air and Water Emissions 2,207,262 1,052,995 734,693 726,120 632,791 628,789 620,628 579,198 531,148 524,899 Table 5. Top 10 U.S. Counties for Air and Water Releases of Carcinogens, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 County HARRIS GALVESTON GEORGETOWN BRAZORIA JEFFERSON JEFFERSON COWLITZ PALM BEACH MORGAN MONROE State TX TX SC TX TX KY WA FL AL NY Total Air and Water Emissions 2,557,944 2,383,244 1,052,996 928,811 927,624 832,951 756,248 726,365 707,188 672,782 DEVELOPMENTAL AND REPRODUCTIVE TOXICANTS Scientists have shown that exposure to some toxic chemicals can impede the proper physical and mental development of young children. Potential developmental health effects cover a wide range of conditions including fetal death, structural defects such as cleft lip/cleft palate and heart abnormalities, and functional defects such as neurological, hormonal or immune system problems. Less is known about the developmental impacts of many toxic chemicals than about their carcinogenicity, in part because developmental effects have been less widely studied and in part because the mechanism by which toxic substances can affect development is complex. Based on available knowledge, the state of California has listed more than 250 substances as known to cause developmental disorders under Proposition 65. The TRI program does not require industries to report their releases of all of these substances. Toxic substances also have the potential to impair the male or female reproductive 10 system, leading to sterility, spontaneous abortion or stillbirth. The state of California currently lists 40 substances as known to cause reproductive disorders in females and 57 substances known to cause reproductive disorders in males. Again, the TRI program does not require industries to report their releases of all of these substances. Few chemicals have been fully tested for their impact on the developing fetus. In fact, of the nearly 3,000 high production volume chemicals studied by EPA in 1998, threefourths (77 percent) did not have publicly available screening-level information on developmental or reproductive toxicity.11 In addition, the timing of exposure during a fetus or child’s development is significant. Maternal exposure to a toxic substance at a critical time during pregnancy may result in a developmental defect, while exposure during another time may not. FINDINGS In 2004, facilities reporting to TRI released more than 96 million pounds of developmental toxicants directly to the air and water. Toluene was the most commonly released developmental toxicant in 2004, totaling 54 million pounds, followed by carbon disulfide at almost 27 million pounds (Table 6). Emissions of toluene and carbon disulfide accounted for 84 percent of all developmental toxicant releases in 2004. Toluene occurs naturally in crude oil and is produced in the process of refining oil and making coke from coal. It also is used in the manufacture of paints, fingernail polish, adhesives and other products. Toluene does not remain in the environment for long, nor does it accumulate within animal tissue. At high levels of exposure, toluene can affect the kidneys, induce light-headedness, or cause unconsciousness or death. Lower level exposures can affect the nervous system and cause fatigue, nausea, and temporary hearing and color vision loss. No evidence links toluene to cancer, but inhalation of high levels of toluene during pregnancy can result in children with birth defects and mental retardation. Less is known about the developmental impacts of low-level exposure during pregnancy.12 Table 6. Developmental Toxicants Released in the Highest Volume to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 Chemical TOLUENE CARBON DISULFIDE BENZENE N-METHYL-2-PYRROLIDONE 1,3-BUTADIENE Total Air and Water Emissions 54,008,597 26,899,459 6,666,412 2,355,373 1,881,877 In 2004, facilities reporting to TRI released almost 38 million pounds of reproductive toxicants directly to the air and water. Carbon disulfide was the reproductive toxicant released in the greatest quantity to air and water in 2004, accounting for more than 70 percent of all reproductive toxicant emissions (Table 7). Carbon disulfide is used in various manufacturing processes and can be lethal at high levels of exposure due to impacts on the nervous system. Animal studies suggest that carbon disulfide can affect the normal functions of the brain, liver and heart and can lead to birth defects and neonatal death.13 Table 7. Reproductive Toxicants Released in the Highest Volume to Air and Water, 2004 (pounds)14 Rank 1 2 3 4 5 Chemical CARBON DISULFIDE BENZENE 1,3-BUTADIENE LEAD COMPOUNDS ETHYLENE OXIDE Total Air and Water Emissions 26,899,459 6,666,412 1,881,877 1,031,090 335,054 11 The chemical industry released the most developmental and reproductive toxicants to air and water in 2004, accounting for almost a third (31 percent) of developmental toxicant releases and more than half (57 percent) of reproductive toxicant releases (Tables 8 and 10). Within the chemical industry, the cellulosic manmade fibers sector – which includes the manufacture of acetate and rayon fibers for clothing – was responsible for the most pollution. This sector uses large amounts of carbon disulfide to treat cellulose in the manufacture of rayon. In Lowland, Tennessee, the Liberty Fibers facility, which manufactures rayon staple fiber products, released more than 14.4 million pounds of carbon disulfide to the air and water in 2004. Four of the 10 facilities releasing the most developmental and reproductive toxicants belong to the rubber and plastic products industry (Tables 9 and 11). Teepak LLC and Viskase Corp. produce cellulose, fibrous and plastic casings for the packaging of meat; Spontex Inc. makes wiping and scouring products (such as sponges) and rubber gloves. Each of these facilities released large amounts of carbon disulfide in 2004. Table 8. Industries Releasing the Most Developmental Toxicants to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 Industry Chemicals and Allied Products Rubber and Miscellaneous Plastics Products Printing, Publishing, and Allied Industries Paper and Allied Products Petroleum Refining and Related Industries Transportation Equipment Primary Metal Industries Lumber and Wood Products, Except Furniture Total Air and Water Emissions 29,723,637 15,026,397 12,445,438 9,626,332 6,983,611 5,439,134 2,237,833 1,843,622 9 10 Fabricated Metal Products, Except Machinery and Transportation Equipment Furniture and Fixtures 1,768,415 1,648,780 The printing and publishing industry ranked third for emissions of developmental toxicants. Commercial printing facilities using the gravure printing process for long runs of multi-colored products such as food packaging, wallpaper, wrapping paper, magazines, and greeting cards, often rely on toluene-based ink. The Quebecor World Memphis Corp. commercial printing facility in Dickson, Tennessee released more toluene than any other facility in this industry—more than 1.5 million pounds. Table 9. Facilities Releasing the Most Developmental Toxicants to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Facility LIBERTY FIBERS CORP TEEPAK LLC INTERTAPE POLYMER GROUP VISKASE CORP QUEBECOR WORLD MEMPHIS CORP. VISKASE CORP SPONTEX INC. SHURTAPE TECHNOLOGIES QUEBECOR WORLD RICHMOND INC INNOVIA FILMS INC City LOWLAND DANVILLE COLUMBIA LOUDON DICKSON OSCEOLA COLUMBIA HICKORY RICHMOND TECUMSEH State TN IL SC TN TN AR TN NC VA KS Total Air and Water Emissions 14,410,790 3,555,300 2,244,218 2,226,146 1,510,219 1,428,423 1,308,128 1,127,803 1,123,901 1,115,957 Table 10. Industries Releasing the Most Reproductive Toxicants to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Industry Chemicals and Allied Products Rubber and Miscellaneous Plastics Products Petroleum Refining and Related Industries Paper and Allied Products Primary Metal Industries Stone, Clay, Glass, and Concrete Products National Security and International Affairs Food and Kindred Products Electric, Gas, and Sanitary Services Wholesale Trade, Non-Durable Goods Total Air and Water Emissions 21,496,968 8,935,031 2,160,364 1,214,972 1,190,040 627,176 610,280 449,115 255,709 229,450 12 Table 11. Facilities Releasing the Most Reproductive Toxicants to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Facility LIBERTY FIBERS CORP TEEPAK LLC VISKASE CORP VISKASE CORP SPONTEX INC. INNOVIA FILMS INC U.S. AIR FORCE DYESS AFB COLUMBIAN CHEMICALS CO 3M CO TONAWANDA COLUMBIAN CHEMICALS CO City LOWLAND DANVILLE LOUDON OSCEOLA COLUMBIA TECUMSEH DYESS AFB PROCTOR TONAWANDA ULYSSES State TN IL TN AR TN KS TX WV NY KS Total Air and Water Emissions 14,410,776 3,555,300 2,226,146 1,428,423 1,308,128 951,757 524,899 486,973 406,000 359,006 Tennessee ranked first in overall releases of both developmental and reproductive toxicants, followed by Texas and Illinois (Figures B and C). These three states accounted for more than 40 percent of the nation’s developmental toxicant releases and more than 70 percent of the reproductive toxicant releases. Tennessee, home to several facilities in the rubber and printing industries and the facility releasing the most developmental and reproductive toxicants, contributed almost a quarter (24 percent) of the nation’s releases of developmental toxicants and almost half (48 percent) of the nation’s releases of reproductive toxicants. See Appendices D and E for a list of all states with facilities releasing developmental and reproductive toxicants to air and water in 2004. Figure B. Air and Water Releases of Developmental Toxicants by State, 2004 Note: Hawaii reported 32,000 pounds of developmental toxicants released to air and water in 2004; Alaska reported almost 58,000 pounds. 13 Figure C. Air and Water Releases of Reproductive Toxicants by State, 2004 Note: Hawaii reported almost 17,000 pounds of reproductive toxicants released to air and water in 2004; Alaska reported almost 33,000 pounds. Releases of developmental and reproductive toxicants are quite concentrated geographically. In 2004, 40 percent of all air and water releases of developmental toxicants and 75 percent of all air and water releases of reproductive toxicants occurred within just 20 zip codes (Tables 12 and 13). Zip code 37778 in Lowland, Tennessee, home to the Liberty Fibers Corp., ranked first for total releases of both developmental and reproductive toxicants to air and water. Similarly, zip code 61832 in Danville, Illinois, home to the Teepak LLC facility discussed earlier, ranked second for total releases of both developmental and reproductive toxicants to air and water. Table 12. Top 10 U.S. Zip Codes for Air and Water Releases of Developmental Toxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Zip Code 37778 61832 29201 37774 37055 72370 38401 28601 23228 66542 City LOWLAND DANVILLE COLUMBIA LOUDON DICKSON OSCEOLA COLUMBIA HICKORY RICHMOND TECUMSEH State TN IL SC TN TN AR TN NC VA KS Total Air and Water Emissions 14,410,790 3,555,300 2,253,649 2,226,210 1,519,851 1,428,423 1,308,483 1,144,614 1,124,656 1,116,113 14 See Appendices F and G for a list of the 100 zip codes reporting the most releases of developmental and reproductive toxicants, respectively, to air and water in 2004. Table 13. Top 10 U.S. Zip Codes for Air and Water Releases of Reproductive Toxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Zip Code 37778 61832 37774 72370 38401 66542 79607 26055 14150 67880 City LOWLAND DANVILLE LOUDON OSCEOLA COLUMBIA TECUMSEH DYESS AFB PROCTOR TONAWANDA ULYSSES State TN IL TN AR TN KS TX WV NY KS Total Air and Water Emissions 14,410,776 3,555,300 2,226,209 1,428,423 1,308,478 951,849 524,899 486,973 416,892 359,006 Similarly, 43 percent of all air and water releases of developmental toxicants reported to TRI occurred within just 20 U.S. counties. Four Tennessee counties—Hamblen, Loudon, Dickson, and Maury—ranked in the top 10 counties for most air and water emissions of developmental toxicants in 2004 (Table 14). Almost 80 percent of all air and water releases of reproductive toxicants occurred within just 20 U.S. counties. Three counties in Tennessee and three in Texas landed in the top 10 for most releases of reproductive toxicants (Table 15). See Appendices H and I for a list of the 100 counties releasing the most developmental and reproductive toxicants, respectively, to air and water in 2004. Table 14. Top 10 U.S. Counties for Air and Water Releases of Developmental Toxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 County HAMBLEN VERMILION HARRIS RICHLAND LOUDON DICKSON MISSISSIPPI JEFFERSON MAURY CATAWBA State TN IL TX SC TN TN AR TX TN NC Total Air and Water Emissions 14,578,261 3,621,127 2,346,750 2,258,044 2,226,212 1,519,851 1,430,888 1,390,937 1,335,292 1,174,320 Table 15. Top 10 U.S. Counties for Air and Water Releases of Reproductive Toxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 County HAMBLEN VERMILION LOUDON MISSISSIPPI HARRIS MAURY SHAWNEE JEFFERSON TAYLOR MARSHALL State TN IL TN AR TX TN KS TX TX WV Total Air and Water Emissions 14,410,776 3,593,888 2,226,211 1,429,962 1,351,884 1,309,932 951,860 588,806 524,899 494,578 SUSPECTED NEUROTOXICANTS Exposure to certain chemical substances can cause adverse effects on the brain or central nervous system. While some substances – such as lead and mercury – have long been known to impair central nervous system function, many other substances have not been fully tested for their neurological effects. Substances toxic to the central nervous system can cause confusion, fatigue, 15 irritability, and other behavioral changes as well as degenerative diseases of the brain (encephalopathy). Chemicals that harm the peripheral nervous system may affect how nerves carry sensory information and motor impulses from the brain to the rest of the body, leading to weakness or tingling in the limbs and loss of coordination.15 No government agency maintains an authoritative list of neurotoxicants. Environmental Defense, however, has compiled a comprehensive list of substances suspected by government or academic researchers to cause neurological problems.16 The TRI program does not require industries to report their releases of all of these substances. FINDINGS In 2004, facilities reporting to TRI released more than 826 million pounds of suspected neurotoxicants directly to the air and water. Methanol was the most commonly released suspected neurotoxicant in 2004, totaling more than 177 million pounds, followed by ammonia at more than 135 million pounds (Table 16). Together, these chemicals accounted for more than one third (38 percent) of all neurotoxicant releases in 2004. Methanol is used as a solvent in adhesives, cleaners and inks; forms from the combustion of plastics and other wastes; and is present in automobile exhaust. At high levels of exposure, methanol can cause headaches, loss of muscle coordination, vision problems, blindness or death. Exposure to methanol also can result in nerve damage, and because the chemical is only slowly eliminated from the body, repeated lowlevel exposures can have severe effects.17 Table 16. Suspected Neurotoxicants Released in the Highest Volume to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 Chemical METHANOL AMMONIA HYDROGEN FLUORIDE TOLUENE STYRENE Total Air and Water Emissions 177,613,616 135,563,847 71,959,637 54,008,597 51,858,677 The chemical industry released the most suspected neurological toxicants in 2004, accounting for a quarter (26 percent) of all releases (Table 17). Within the chemical industry, the nitrogenous fertilizers sector was one of the largest air and water polluters, releasing large amounts of ammonia and methanol. This sector manufactures ammonia fertilizer compounds and anhydrous ammonia, nitric acid, ammonium nitrate, ammonium sulfate and nitrogen solutions, urea, and natural organic fertilizers.18 The Terra Nitrogen facility in Sergeant Bluff, Iowa released more than 6.4 million pounds of ammonia to the air in 2004, ranking the facility third in the country for total releases of neurotoxicants (Table 18). Table 17. Industries Releasing the Most Suspected Neurotoxicants to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Industry Chemicals and Allied Products Paper and Allied Products Electric, Gas, and Sanitary Services Transportation Equipment Rubber and Miscellaneous Plastics Products Food and Kindred Products Petroleum Refining and Related Industries Primary Metal Industries Fabricated Metal Products, Except Machinery and Transportation Equipment Stone, Clay, Glass, and Concrete Products Total Air and Water Emissions 214,855,785 169,309,749 67,434,469 58,507,561 56,704,211 42,937,605 38,240,105 35,592,989 30,370,845 28,458,766 16 Table 18. Facilities Releasing the Most Suspected Neurotoxicants to Air and Water, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Facility LIBERTY FIBERS CORP BP TEXAS CITY REFINERY TERRA NITROGEN CF INDUSTRIES INC SUN CHEMICAL BUSHY PARK MILLENNIUM INORGANIC CHEMICALS KOCH NITROGEN CO INTERNATIONAL PAPER INTERNATIONAL PAPER INTERNATIONAL PAPER City LOWLAND TEXAS CITY SERGEANT BLUFF DONALDSONVILLE GOOSE CREEK ASHTABULA BEATRICE MANSFIELD RIEGELWOOD QUEEN CITY State TN TX IA LA SC Total Air and Water Emissions 14,463,493 6,888,560 6,432,455 6,173,200 5,000,105 OH NE LA NC TX 4,856,250 4,805,810 4,695,750 4,592,300 4,372,316 The paper industry ranked second in releases of suspected neurotoxicants in 2004. Pulp, paper, and paperboard mills release large amounts of methanol, a byproduct of the pulping and washing processes. The International Paper paperboard mill in Mansfield, Louisiana released the second most methanol to air of any facility—more than 4.2 million pounds to the air and water—in addition to more than 250,000 pounds of ammonia and other chemicals. Ranking third for neurotoxicant releases, the electric services industry (comprised mainly of power plants) accounted for about 80 percent of all hydrogen fluoride released into the air in 2004. Almost all of this pollution comes from the combustion of coal, which contains small amounts of fluoride compounds that form hydrogen fluoride when burned.19 In Cartersville, Georgia, Georgia Power’s coal-fired Bowen power plant released 1.5 million pounds of hydrogen fluoride, the most of any facility in the country. 2004 (Figure D). Georgia is home to 10 power plants releasing more than 4.6 million pounds of suspected neurotoxicants and more than a dozen pulp, paper, and paperboard facilities releasing more than 18 million pounds of suspected neurotoxicants to air and water in 2004. Similarly, Ohio is home to 25 power plants releasing more than five million pounds of suspected neurotoxicants and more than 150 chemical facilities releasing almost 14 million pounds of suspected neurotoxicants to air and water in 2004. See Appendix J for a list of all states with facilities releasing suspected neurotoxicants to air and water in 2004. In 2004, 13 percent of all air and water releases of suspected neurotoxicants reported to TRI occurred within just 20 zip codes. Zip code 37778 in Lowland, Tennessee, home to the Liberty Fibers Corp., ranked first for total releases of suspected neurotoxicants to air and water, followed by 77590 in Texas City, Texas and 44004 in Ashtabula, Ohio (Table 19). See Appendix K for a list of the 100 zip codes reporting the most releases of suspected neurotoxicants to air and water in 2004. Similarly, almost 17 percent of all air and water releases of suspected neurotoxicants reported to TRI occurred within just 20 U.S. counties. Three Texas counties—Harris, Galveston, and Jefferson—ranked in the top 10 counties for most air and water emissions of suspected neurotoxicants in 2004 (Table 20). See Appendix L for a list of the 100 counties reporting the most releases of suspected neurotoxicants to air and water in 2004. Texas, Tennessee, Georgia, Louisiana, and Ohio ranked highest for overall releases of suspected neurotoxicants to air and water in 17 Figure D. Air and Water Releases of Suspected Neurotoxicants by State, 2004 Note: Hawaii reported more than 310,000 pounds of neurotoxicants released to air and water in 2004; Alaska reported almost 1.9 million pounds. Table 19. Top 10 U.S. Zip Codes for Air and Water Releases of Suspected Neurotoxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Zip Code 37778 77590 44004 70346 51054 29445 68310 71052 28456 30901 City LOWLAND TEXAS CITY ASHTABULA DONALDSONVILLE SERGEANT BLUFF MOUNT HOLLY/GOOSE CREEK BEATRICE MANSFIELD RIEGELWOOD AUGUSTA State TN TX OH LA IA SC NE LA NC GA Total Air and Water Emissions 14,463,493 7,292,059 6,952,997 6,935,633 6,791,533 6,245,054 4,881,133 4,748,082 4,703,218 4,655,458 Table 20. Top 10 U.S. Counties for Air and Water Releases of Suspected Neurotoxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 County HAMBLEN HARRIS ASCENSION GALVESTON BERKELEY RICHMOND ASHTABULA JEFFERSON WOODBURY LOS ANGELES State TN TX LA TX SC GA OH TX IA CA Total Air and Water Emissions 14,702,488 14,231,090 9,705,246 8,717,524 7,506,926 7,339,191 7,142,731 7,089,354 7,037,963 5,214,571 18 SUSPECTED RESPIRATORY TOXICANTS Exposure to certain toxic substances can cause adverse effects on the respiratory system ranging in severity from irritation to bronchitis to cancer. The link between exposure to asbestos fibers and cigarette smoke and disorders such as lung cancer and emphysema is well documented. In addition, exposure to ground ozone, a common air pollutant, has been linked to the onset of asthma attacks and to the development of As is the case with asthma itself.20 neurological disorders, the respiratory impacts of most toxic substances have been subject to less study, and no government agency has compiled a definitive list of respiratory toxicants. Environmental Defense, however, has compiled a list of suspected respiratory toxicants based on a variety of scientific sources.21 The TRI program does not require industries to report their releases of all of these substances. FINDINGS In 2004, facilities reporting to TRI released almost 1.5 billion pounds of suspected respiratory toxicants directly to the air. Aerosols of hydrochloric acid were released in the greatest quantities, representing more than one of every three pounds of suspected respiratory toxicants released in 2004 (Table 21). Hydrochloric acid is used for cleaning, pickling, and electroplating metals; in refining mineral ores; in petroleum well extraction; in leather tanning; and in producing polymers and plastics, rubber, fertilizers, dyes, and pigments.22 Electric power plants also release hydrochloric acid to the air in large quantities. Hydrochloric acid is highly corrosive and irritating to the eyes and the respiratory tract. Chronic occupational exposure has been linked to gastritis, chronic bronchitis and dermatitis in workers, while long-term, low-level exposure has been linked to dental erosion.23 Table 21. Suspected Respiratory Toxicants Released in the Highest Volume to the Air, 2004 (pounds) Rank 1 2 3 4 5 Chemical HYDROCHLORIC ACID AEROSOLS METHANOL SULFURIC ACID AEROSOLS AMMONIA HYDROGEN FLUORIDE Total Air Emissions 558,372,304 166,647,387 140,715,422 129,307,197 71,954,379 The electric services industry, which includes electric power plants, was responsible for the greatest releases of suspected respiratory toxicants in 2004 (Table 22). This industry accounted for 46 percent of all suspected respiratory toxicant releases nationwide and 90 percent of all releases of hydrochloric acid. Nine of the 10 facilities releasing the most respiratory toxicants were power plants (Table 23). Since coal contains trace amounts of chloride, coal-burning electric utilities release chloride into the air, which can combine with hydrogen in the air to form hydrogen chloride. Upon contact with water, the hydrogen chloride forms hydrochloric acid.24 Table 22. Industries Releasing the Most Suspected Respiratory Toxicants to Air, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Industry Electric, Gas, and Sanitary Services Chemicals and Allied Products Paper and Allied Products Transportation Equipment Rubber and Miscellaneous Plastics Products Petroleum Refining and Related Industries Food and Kindred Products Primary Metal Industries Stone, Clay, Glass, and Concrete Products Fabricated Metal Products, Except Machinery and Transportation Equipment Total Air and Water Emissions 683,233,869 208,965,306 180,398,372 59,980,420 56,684,176 50,120,478 47,745,821 44,884,498 37,183,096 31,458,836 19 Table 23. Facilities Releasing the Most Suspected Respiratory Toxicants to Air, 2004 (pounds) Rank Facility City State Total Air Emissions 1 U.S. TVA JOHNSONVILLE FOSSIL PLANT NEW JOHNSONVILLE TN 17,048,396 2 RELIANT ENERGY KEYSTONE POWER PLANT SHELOCTA PA 16,403,890 3 AMERICAN ELECTRIC POWER AMOS PLANT WINFIELD WV 15,708,386 4 BOWEN STEAM ELECTRIC GENERATING PLANT CARTERSVILLE GA 15,457,168 5 LOWLAND TN 14,769,926 6 LIBERTY FIBERS CORP AMERICAN ELECTRIC POWER KAMMER/ MITCHELL PLANTS MOUNDSVILLE WV 14,272,016 7 DUKE ENERGY BELEWS CREEK STEAM STN BELEWS CREEK NC 13,661,595 8 MARSHALL STEAM STATION CAROLINA POWER & LIGHT CO ROXBORO STEAM ELECTRIC PLANT PROGRESS ENERGY CRYSTAL RIVER ENERGY COMPLEX TERRELL NC 13,571,617 SEMORA NC 12,160,544 CRYSTAL RIVER FL 11,960,774 9 10 Ohio, North Carolina, Tennessee, Texas and Pennsylvania ranked highest in respiratory toxicant releases to air in 2004 (Figure E). These states are home to some of the country’s largest coal-burning and polluting power plants, as shown in Table 23, as well as chemical facilities and refineries. Ohio alone is home to seven power plants releasing at least four million pounds of hydrochloric acid in 2004. See Appendix M for a list of all states with facilities releasing suspected respiratory toxicants to the air in 2004. Figure E. Air Releases of Suspected Respiratory Toxicants by State, 2004 Note: Hawaii reported more than 2.3 million pounds of respiratory toxicants released to air in 2004; Alaska reported more than 1.6 million pounds. 20 Zip code 37134 in New Johnsonville, Tennessee ranked first in the nation for air releases of suspected respiratory toxicants, followed by zip codes in Shelocta, Pennsylvania and Winfield, West Virginia (Table 24); these zip codes are home to the three power plants releasing the most suspected respiratory toxicants to air in 2004, as shown in Table 23. Three West Virginia zip codes fall in the top 10 for most respiratory toxicant releases. Similarly, Jefferson County, Ohio — home to FirstEnergy’s W. H. Sammis power plant and American Electric Power’s Cardinal power plant — falls at the top of the list of counties reporting the highest releases of suspected respiratory toxicants, followed by Armstrong County, Pennsylvania. One-fifth (20 percent) of all air and water releases of suspected respiratory toxicants occurred within just 20 U.S. counties (Table 25). See Appendix N for a list of the 100 zip codes and Appendix O for the 100 counties reporting the most releases of suspected respiratory toxicants to the air in 2004. Table 24. Top 10 U.S. Zip Codes for Air Emissions of Suspected Respiratory Toxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Zip Code 37134 15774 25213 30120 37778 26041 27009 28682 45144 25265 City NEW JOHNSONVILLE SHELOCTA WINFIELD CARTERSVILLE LOWLAND MOUNDSVILLE BELEWS CREEK TERRELL MANCHESTER NEW HAVEN State TN PA WV GA TN WV NC NC OH WV Total Air Emissions 17,185,681 16,403,890 15,708,386 15,476,036 14,769,926 14,312,502 13,661,597 13,571,617 12,977,392 12,526,073 Table 25. Top 10 U.S. Counties for Air Emissions of Suspected Respiratory Toxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 County JEFFERSON ARMSTRONG HUMPHREYS HARRIS PERSON MARSHALL PUTNAM BARTOW CATAWBA HAMBLEN State OH PA TN TX NC WV WV GA NC TN Total Air Emissions 21,850,211 19,514,515 18,805,656 17,672,267 16,396,477 16,017,366 15,716,564 15,660,124 15,016,129 15,009,961 DIOXINS EPA added the chemical class known as dioxins to the Toxics Release Inventory beginning in the 2000 reporting year. Long regarded as among the most toxic chemicals known to science, dioxins can alter the growth and development of cells and lead to adverse effects on reproduction and development, suppression of the immune system, and cancer. In fact, EPA estimates that the cancer risk from dioxins in levels already present in the general public is approximately 1-per-1,000.25 Chlorine bleaching of pulp and paper, certain types of chemical manufacturing and processing, and other industrial processes all can create small quantities of dioxins. Dioxins are treated separately from other chemicals in this report because minute quantities of dioxins are dangerous to human health. As a result, EPA requires facilities to report their dioxin releases to TRI in units of grams rather than pounds. Including dioxins with other toxicants would downplay the severe consequences that even small releases of dioxins can have on human health and the environment. 21 Table 26. Industries Releasing the Most Dioxins to Air and Water, 2004 (grams) FINDINGS U.S. facilities nationwide reported releasing 2,631 grams of dioxins to the air and water during 2004. The chemical industry released the most dioxins to air and water, accounting for almost half (49 percent) of all air and water emissions of dioxins (Table 26). The electric power sector and paper industry followed, together accounting for almost a third (31 percent) of the dioxin releases. The most dioxin releases occurred in Texas, Louisiana, Alabama, New Hampshire and Arkansas (Figure F). These states are home to numerous chemical facilities, pulp and paperboard mills, petroleum refineries, and large coal-burning power plants. Freeport, Texas and Plaquemine, Louisiana are home to the two facilities—both owned by Dow Chemical—that released the most dioxins in 2004 (Table 27). These two facilities account for almost a third (31 percent) of the dioxins released across the country in 2004. See Appendix P for a list of all states home to facilities reporting dioxin releases in 2004. Rank 1 2 3 4 5 Industry Chemicals and Allied Products Electric, Gas, and Sanitary Services Paper and Allied Products Primary Metal Industries Lumber and Wood Products, Except Furniture Total Air and Water Emissions 1,291.33 606.55 208.30 192.70 189.77 Table 27. Facilities Releasing the Most Dioxins to Air and Water, 2004 (grams) Rank 1 2 3 4 5 6 7 8 9 10 Facility DOW CHEMICAL CO FREEPORT FACILITY DOW CHEMICAL CO LOUISIANA DIV INNOVENE POLYETHYLENE N.A. TILLOTSON RUBBER CO. CAHABA PRESSURE TREATED FOREST PRODS VULCAN CHEMICALS DOMTAR INDUSTRIES INC ASHDOWN MILL PPG INDUSTRIES INC KOPPERS INC HUXFORD POLE & TIMBER CO. INC. City FREEPORT PLAQUEMINE LA PORTE DIXVILLE NOTCH BRIERFIELD WICHITA ASHDOWN WESTLAKE GRENADA HUXFORD State TX LA TX NH AL KS AR LA MS AL Total Air and Water Emissions 524.00 298.47 235.86 151.27 74.97 57.01 43.77 39.78 36.77 27.85 Figure F. Dioxin Releases to Air and Water by State, 2004 Note: Hawaii reported 4 grams of dioxins released to air and water in 2004; Alaska reported 8 grams. 22 These dioxin releases are quite concentrated within a relatively small number of localities, especially in the Gulf of Mexico region. In 2004, almost two-thirds (62 percent) of all air and water releases of dioxins reported to TRI occurred within just 20 zip codes (Table 28). Zip code 77541 in Freeport, Texas saw the highest releases of dioxins to air and water, followed by zip codes in Plaquemine, Louisiana, La Porte, Texas, and Dixville Notch, New Hampshire. Similarly, almost 65 percent of all air and water releases of dioxins occurred within just 20 counties, half of which are located in the Gulf region (Table 29). See Appendix Q for a list of the 100 zip codes and Appendix R for the 100 counties reporting the most dioxin releases to the air and water in 2004. Table 28. Top 10 U.S. Zip Codes for Dioxin Releases to Air and Water, 2004 (grams) Rank 1 2 3 4 5 6 7 8 9 10 Zip Code 77541 70765 77571 03576 35035 67215 71822 70669 38960 36543 City FREEPORT PLAQUEMINE LA PORTE DIXVILLE NOTCH BRIERFIELD WICHITA ASHDOWN WESTLAKE GRENADA HUXFORD State TX LA TX NH AL KS AR LA MS AL Total Air and Water Emissions 525.37 298.47 239.37 151.27 74.97 57.01 43.77 43.24 36.77 27.85 Table 29. Top 10 U.S. Counties for Dioxin Releases to Air and Water, 2004 (grams) Rank 1 2 3 4 5 6 7 8 9 10 County BRAZORIA IBERVILLE HARRIS COOS BIBB SEDGWICK LITTLE RIVER CALCASIEU ESCAMBIA GRENADA State TX LA TX NH AL KS AR LA AL MS Total Air and Water Emissions 525.87 301.64 254.91 151.86 74.97 57.51 47.93 43.33 39.12 37.22 23 TOXIC RELEASES TO LAND The mining industry dominates land releases of carcinogens, developmental toxicants and reproductive toxicants – largely due to the on-site land disposal of hundreds of millions of pounds of compounds including lead, arsenic and chromium. We decided to separate the toxic releases to air and water from the toxic releases to land because most mining facilities are in remote locations with a small surrounding population. Although the mining industry’s pollution poses long-term threats to the environment and public health, the massive releases of toxic substances to land would have deemphasized the threats posed by less voluminous air and water discharges nationwide. In 2004, facilities reporting to TRI released more than 608 million pounds of carcinogens, developmental toxicants or reproductive toxicants to land. Land releases include all the chemicals disposed on land within the boundaries of the reporting facility and can include on-site landfills, surface impoundments (uncovered holding ponds), land treatment, and accidental spills or leaks. The metal mining industry, led by the lead and zinc, gold, silver, and copper sectors, was responsible for about 485 million pounds (80 percent) of these releases (Table 30). The electric services sector had the largest non-mining sector releases to land. The 10 facilities releasing the most toxic substances to land belong to the metal mining industry, led by the Red Dog mine in Kotzebue, Alaska and the Coeur Rochester mine in Lovelock, Nevada (Table 31). Table 30. Industries with Most Land Releases of Carcinogens, Developmental Toxicants and Reproductive Toxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 Industry Metal Mining Electric, Gas, and Sanitary Services Primary Metal Industries Chemicals and Allied Products National Security and International Affairs Coal Mining Stone, Clay, Glass, and Concrete Products Nonclassifiable Establishments Paper and Allied Products Electronic and Other Electrical Equipment/ Components, Except Computer Equipment Total OnSite Land Releases 485,420,236 85,267,251 21,476,222 9,439,722 2,279,833 1,420,598 1,050,941 889,779 449,465 194,170 Table 31. Facilities with Most Land Releases of Carcinogens, Developmental Toxicants and Reproductive Toxicants, 2004 (pounds) Facility City State Total OnSite Land Releases 1 RED DOG OPERATIONS KOTZEBUE AK 131,857,483 2 LOVELOCK NV 85,302,846 3 COEUR ROCHESTER INC KENNECOTT UTAH COPPER MINE CONCENTRATORS & POWER PLANT COPPERTON UT 52,554,078 4 NEWMONT MINING TWIN CREEKS MINE GOLCONDA NV 39,000,000 5 BARRICK GOLDSTRIKE MINES INC ELKO NV 22,594,720 6 NEWMONT MINING LONE TREE MINE VALMY NV 20,000,790 7 NEWMONT MINING CARLIN SOUTH AREA CARLIN NV 14,000,000 8 BUICK MINE/MILL MO 11,307,924 MT 9,219,699 MO 8,173,767 Rank 9 MONTANA TUNNELS MINING INC BOSS JEFFERSON CITY 10 FLETCHER MINE/MILL BUNKER Two-thirds (67 percent) of the land releases of carcinogens, developmental toxicants and reproductive toxicants were lead or lead compounds (Table 32). Exposure to lead can affect almost every organ and system in the human body, especially the central nervous system. Exposure to low doses of lead can cause IQ deficits, attention deficit 24 hyperactivity disorder, and deficits in vocabulary, fine motor skills, reaction time, The and hand-eye coordination.26 developing brains and nervous systems of children are particularly sensitive to the damaging effects of lead. Table 32. Carcinogens, Developmental Toxicants and Reproductive Toxicants Released in the Highest Volume to Land, 2004 (pounds)27 Rank 1 2 3 4 5 Chemical LEAD COMPOUNDS ARSENIC COMPOUNDS CHROMIUM COMPOUNDS NICKEL COMPOUNDS LEAD Total OnSite Land Releases 395,498,060 115,570,487 28,959,574 22,266,594 11,759,696 The states receiving the most toxic releases to land are often the most sparsely populated. Nevada, Alaska, and Utah ranked first, second and third for total land releases of carcinogens, developmental toxicants and reproductive toxicants in 2004 (Figure G), accounting for 71 percent of the land releases of these substances. The mining industry accounts for the vast majority of the toxic releases to land in these states. See Appendix S for a list of all states with facilities reporting land releases of carcinogens, developmental toxicants and reproductive toxicants in 2004. Figure G. Land Releases of Carcinogens, Developmental Toxicants and Reproductive Toxicants, 2004 (pounds) Note: Hawaii released more than 125,000 pounds of toxic substances to land in 2004. 25 The largest land releases of carcinogens, developmental toxicants and reproductive toxicants occurred in relatively remote areas. As shown in Table 33, zip code 99752, located 90 miles north of Kotzebue, Alaska and home to the Red Dog zinc and lead mine, ranked first for total releases of these substances to land, followed by zip code 89419 in Lovelock, Nevada (home to the Coeur Rochester silver mine) and 84006 in Copperton/Bingham Canyon, Utah (home to the Kennecott Utah copper mine). Four Nevada counties—Pershing, Humboldt, Elko, and Eureka—fell in the top 10 counties with the most land releases of carcinogens, developmental toxicants and reproductive toxicants (Table 34). See Appendix T for a list of the 100 zip codes and Appendix U for the list of the 100 counties reporting the most land releases of carcinogens, developmental toxicants and reproductive toxicants in 2004. Table 33. Top 10 U.S. Zip Codes for Land Releases of Carcinogens, Developmental Toxicants and Reproductive Toxicants, 2004 (pounds) Rank 1 2 Zip Code 99752 89419 3 4 5 6 7 8 9 10 84006 89414 89803 89438 89822 63629 65440 84044 City KOTZEBUE LOVELOCK BINGHAM CANYON/ COPPERTON GOLCONDA/MIDAS ELKO VALMY CARLIN BUNKER BOSS MAGNA State AK NV Total OnSite Land Releases 135,329,476 85,322,626 UT NV NV NV NV MO MO UT 53,818,352 42,382,733 35,016,558 23,485,855 18,790,206 13,358,616 12,435,901 11,398,156 Table 34. Top 10 U.S. Counties for Land Releases of Carcinogens, Developmental Toxicants and Reproductive Toxicants, 2004 (pounds) Rank 1 2 3 4 5 6 7 8 9 10 County NORTHWEST ARCTIC PERSHING HUMBOLDT SALT LAKE ELKO EUREKA REYNOLDS IRON JEFFERSON SILVER BOW State AK NV NV UT NV NV MO MO MT MT Total OnSite Land Releases 135,329,476 85,929,456 65,757,170 65,216,816 36,696,303 18,790,206 14,598,233 12,435,901 9,574,327 8,940,004 26 BUSH ADMINISTRATION WEAKENS THE TOXICS RELEASE INVENTORY A s this report demonstrates, facilities across the country continue to release millions of pounds of toxic chemicals known or suspected to cause serious health effects. The Toxics Release Inventory program plays a pivotal role in providing for the public’s right-to-know about the use and release of these toxic chemicals. Regrettably, the Bush administration recently weakened the TRI program by reducing the information available to the public about toxic chemicals released into communities. BACKGROUND: TRI REPORTING REQUIREMENTS The TRI program requires companies that manage or release toxic chemicals above established thresholds to disclose these activities to EPA in an annual reporting process. This annual reporting, made for each toxic chemical present at a facility and covered by the program, provides EPA with a snapshot of toxic waste management and pollution activities at a particular facility. Once annual reports are submitted, EPA compiles and disseminates the data on its website for public review. TRI disclosure requirements apply only to certain classes of industrial facilities that employ more than 10 full time employees and release, store or manage any one of 650 listed toxic chemicals in amounts that exceed established reporting thresholds.28 Depending on the type and quantity of toxic chemical, facilities comply with reporting requirements by submitting one of two forms: a short “Form A” certification statement or a detailed “Form R” report. The Form R report provides a full disclosure that captures FORM R REPORT VS. FORM A CERTIFICATION Form R Report: Includes the name of toxic chemical, the amount released to the environment (delineated by total releases to water, underground injection wells, air, and disposed to land), the amount recycled, the amount combusted for energy, and the amount transferred offsite (delineated by total sent offsite for disposal, recycling or energy combustion). Form A Certification: Acknowledges that the listed toxic chemical is present at a facility. detailed information about the chemicals released, such as the quantity of the chemical disposed or released onsite to the air, water, or land; injected underground; or transferred for disposal or release offsite.29 Since 1995, however, EPA has allowed facilities to submit the more limited Form A certification statement in lieu of the detailed Form R if they release or manage toxic chemicals in small amounts.30 The Form A only certifies that a toxic chemical is present at a facility but does not contain any of the detailed information about the quantities of the toxic chemical used, released, or managed as waste. According to EPA, “the primary difference between information contained on Form R and the Form A Certification Statement is that the Form R provides details of releases and other waste management (e.g., total quantity of releases to air, water, and land; on- and off-site recycling, treatment, and combustion for 27 energy recovery), while the Form A does not.”31 The Form R reports supply the critical data that enables TRI users to assess when toxic substances are released, where releases occur and in what amounts. Form A only serves to warn the public that a toxic chemical is present at a facility without providing any additional information. FORM A CERTIFICATION STATEMENT ELIGIBILITY Since the Form A certification statement does not provide useful information about the quantity and ultimate disposition of a toxic chemical release, EPA historically has restricted the use of Form A by establishing a low Form A reporting threshold.32 A facility is eligible to use the Form A only when the combined total amount of the waste management and release of a toxic chemical is less than the established reporting threshold. If the combined waste management and release total exceeds the reporting threshold, a facility must complete and submit a detailed Form R report. In addition to reporting thresholds, EPA had disallowed Form A eligibility for a small but dangerous class of chemicals called persistent bioaccumulative toxics (PBTs). PBT chemicals, such as lead and mercury, are treated separately and with greater attention because they remain in the environment for long periods of time, do not readily degrade, and build up or accumulate in body tissue. Because PBTs are dangerous even in small amounts, EPA required facilities to report all PBT releases on detailed Form R reports without regard to threshold levels—until December 2006. BUSH ADMINISTRATION WEAKENS TOXIC RELEASE REPORTING REQUIREMENTS On December 22, 2006, EPA finalized a new rule that will reduce the quantity and quality of toxic chemical data submitted under TRI and available to the public.33 The new rule consists of two major modifications to the reporting requirements for TRI toxic chemicals. DIMINISHED REPORTING FOR PERSISTENT BIOACCUMULATIVE TOXICS The new rule allows, for the first time, facilities to obtain Form A certification for PBT chemicals when the total reportable amount for a PBT does not exceed 500 pounds and the chemical is not disposed or released to the environment.34 Previously, EPA required detailed Form R reporting for all PBT chemicals, regardless of total reportable amount or ultimate disposition. In a 1999 rulemaking, EPA claimed that Form A certification is “insufficient for conducting meaningful analyses on PBT chemicals” and prohibited the use of certification for PBT chemicals.35 The expansion of Form A certification eligibility to PBT chemicals represents a significant divergence from the EPA’s previous position and eliminates currently collected information on the most dangerous and long-lived toxic chemicals. RAISED REPORTING THRESHOLDS FOR TRI CHEMICALS The second change increases the reporting threshold for non-PBT toxic chemicals from 500 pounds to 5,000 pounds per year. The raised threshold permits facilities to forgo detailed reporting and submit only a certification statement if the total reportable amount for a toxic chemical is below 5,000 pounds, provided the total amount of the 28 substance disposed or released to the environment does not exceed 2,000 The new reporting threshold pounds.36 increases by a factor of ten the point at which facilities must report to EPA and will allow facilities to release four times the amount of a toxic chemical without reporting the release to EPA. Accordingly, the raised reporting threshold for non-PBT chemicals appreciably reduces the amount and quality of toxic release data available to the public. Generally, these changes enable facilities to withhold currently reported information about toxic chemicals and restrict public access to information about toxic chemicals released in communities. A preliminary analysis of the changes by the Government Accountability Office estimated that 3,565 facilities would no longer be required to submit information describing the amount and location of toxic chemical releases.37 29 RECOMMENDATIONS T he continued use and release of toxic chemicals presents tangible and serious threats to human health and the environment. Each year, emerging science provides increasing evidence linking chemical exposures to adverse health impacts. Americans have known about the potential threat of toxic releases in their communities for years, but the data on toxic releases reviewed in this report reveal that many communities still confront large-scale releases of substances that are known or suspected to damage public health. Moreover, for many chemicals, crucial data gaps remain in our understanding of how these chemicals interact with humans and may affect our health and well-being. To reduce toxic chemical use and releases in our communities and ensure that these communities have access to information about this pollution, we recommend the following steps. RESTORE PUBLIC ACCESS TO TOXIC RELEASE DATA In order to maintain the quality and quantity of TRI data collected and disseminated to the public, EPA should: Reverse its recent rulemaking extending Form A eligibility to PBT chemicals. As mentioned previously, PBT chemicals do not readily degrade, accumulating in the food chain and in animal and human body tissue. Because even small releases of these chemicals pose a serious threat to human health, EPA should require full disclosure of releases of PBT chemicals. Reverse its recent rulemaking increasing reporting thresholds for all non-PBT TRI chemicals. The sizeable increase in the reporting threshold will have a significant impact on the information available to the public about dozens of toxic chemicals from thousands of facilities in states and communities across the country. Some facilities will not have to provide detailed information on the amounts and locations of toxic chemical releases and disposals, complicating governmental and community efforts to understand and track toxic chemical pollution. IMPROVE TRI DATA QUALITY Although the TRI represents the best source of national and local toxic release and waste management information, EPA could improve the quality of the TRI data. Specifically, the methods used to generate data and the time it takes for EPA to process and publish the data present major limitations for communities and states. In order to improve the quality of TRI data, EPA should: Improve the accuracy of reported toxic release and waste management data. The TRI program does not currently require any specific monitoring of emissions, but instead allows facilities to rely on equations that estimate releases and waste generation during the course of the reporting year. Although facilities are responsible for the accuracy of the TRI data submitted to EPA, relying on emissions estimations may not provide a valid and accurate accounting of toxic data. Instead, EPA should evaluate and require facilities to use continuous monitoring devices, the most effective way to accurately track all quantities of toxic releases. Advances in technology 30 have improved the reliability and reduced the cost of continuous monitoring devices, and many facilities already use such devices to monitor pollution. chemicals, including data on releases of chemical categories of serious concern such as PBTs, carcinogens and hazardous air pollutants. Increase the speed at which EPA processes TRI data and makes it public. EPA did not release TRI data for the 2004 reporting year until April 2006. Delays in releasing data force the public, communities and states to rely on TRI data that is often two to three years old. EPA should expedite TRI data release by promoting full and timely electronic reporting for all covered facilities and by reducing the time that facilities have to confirm data submissions to 60 days. Technological improvements, such as continuous monitoring, also would reduce the time required to calculate and verify toxic release data. Provide a balanced analysis of the data results that highlights troubling findings in addition to positive trends. IMPROVE TRI DATA ANALYSIS When EPA releases TRI data, the agency also provides an analysis of the information in its Public Data Release (PDR). In recent years, EPA has reduced the amount of analysis provided in the PDR. For example, EPA has stopped enumerating a list of the facilities with the highest toxic releases. EPA should implement the following steps to ensure that the public is provided with a useful analysis of the TRI data: Detail the facilities in each industry sector responsible for the most toxic releases and list the U.S. states and counties experiencing the most pollution. Explain in each PDR that TRI does not cover all chemicals or all sources of chemicals; include the percentage of facilities, chemicals, and/or releases that are covered under TRI each year. Develop a TRI data user’s guide for the media and the public. REDUCE CHEMICAL USE The data reported to TRI demonstrate that toxic chemicals are released to the environment in significant quantities nationwide. While the links between some of these chemicals and health problems are uncertain, common sense and the weight of available evidence suggest that prudent steps be taken to reduce the use and release of toxic chemicals nationwide. State and federal governments can play a direct role in reducing toxic emissions to the air and water by strictly enforcing basic pollution laws such as the Clean Air Act and Clean Water Act. Ultimately, however, state and federal governments must address the issue of preventing pollution by encouraging reductions in the use of toxic chemicals and the substitution of safer alternatives. The Massachusetts Toxics Use Reduction Act, which requires reporting of toxic chemical use and the development of plans for use reduction by industry, reduced generation of toxic waste per unit of production by 65 percent between 1990 and 2004 and onsite releases of TRI chemicals by 91 percent.38 Revitalizing pollution prevention efforts at the state and federal levels should be a top policy priority. Provide information on the potential health hazards of the reported toxic 31 REFORM CHEMICALS POLICY Chemicals that are untested or known to be hazardous to human health should not be on the market or in widespread use and distribution. U.S. chemicals policy should ensure that manufacturers and industrial users provide regulatory agencies and the public with adequate information about their products so that agencies can act to protect public health from potentially dangerous substances before damage is done. Currently, manufacturers can put chemicals on the market before detection methods have even been developed to test for the presence of the chemical in air, water, soil, and our bodies. The burden falls on federal and state governments to develop these analytical methods – an expensive and timeconsuming process. The costs of developing analytical methods to test for a chemical’s safety should fall to the manufacturers who stand to profit from the product. Manufacturers should be required to provide all hazard and health-impact information to EPA so the agency can begin to assess the thousands of chemicals currently on the market for which it has little or inadequate data. Manufacturers of chemicals also should be required to conduct an alternatives analysis to determine if they are using the least hazardous chemical for each application. Finally, EPA’s authority to ban or restrict the use of a chemical if it can harm human health must be strengthened. 32 METHODOLOGY A ll data analyzed for this report are from the EPA’s Toxics Release Inventory. Subsequent amendments to TRI reports made by industry following EPA’s release of the 2004 reporting year data may not be reflected in this analysis. We only looked at releases in the 50 states and the District of Columbia and excluded releases in U.S. territories. Health Effects We looked at all of the chemicals and substances reported in 2004 to TRI and categorized them by health effect. We used California’s Proposition 65 list, current as of December 8, 2006, to categorize chemicals as carcinogens, developmental toxicants and/or reproductive toxicants. To identify suspected neurological and respiratory toxicants, we used Environmental Defense’s Scorecard.org website. Environmental Defense’s lists are based primarily on information compiled by EPA, the National Institute for Occupational Safety and Health, the states of California, Massachusetts and New Jersey, and European government agencies, as well as toxicological studies published in scientific journals. In a small number of cases, Environmental Defense conducted supplementary review to identify any remaining potential human health hazards.39 See Appendix V for a list of the chemicals included in this report and associated health effects. Not all chemicals reported to TRI in 2004 fell into these five categories of health concern and therefore are excluded from this report. Some of the excluded chemicals may cause other health effects, ranging from skin disorders to endocrine disruption; other chemicals have little toxicity data available. In cases in which a single chemical was listed, but TRI reports only releases by chemical class, we assumed the entire class causes the listed health effect. For example, releases of polycyclic aromatic compounds are reported to TRI as a class, even though they are listed separately on California’s Proposition 65 list. Also, some chemicals are listed as toxic in certain forms on the Proposition 65 list, but their releases are reported to TRI in the aggregate. For example, several “technical grade” chemicals are listed as carcinogens under Proposition 65, but TRI does not make a similar distinction. Because there is no way to resolve this mismatch, we assumed all substances reported to TRI that are listed on Proposition 65 cause the listed health effect. In cases in which an elemental form of a substance was on the Proposition 65 list, we assumed compounds including the substance also cause the listed health effect. Two specific examples bear mentioning. Proposition 65 includes lead and cadmium as developmental and reproductive toxicants, but not their compounds. Environmental Defense lists lead compounds as recognized developmental and reproductive toxicants and cadmium compounds as suspected developmental and reproductive toxicants based on the inclusion of their elemental forms on the Proposition 65 list. This analysis includes both lead compounds and cadmium compounds in our list of developmental and reproductive toxicants. Industry Analysis Industry analysis is based on the primary, four-digit Standard Industrial Classification (SIC) codes reported by the facilities to TRI. We grouped each facility by its major industry (the first two numbers of the SIC code) as defined by the U.S. Department of Labor.40 Some facilities did not report primary SIC codes and were excluded from the industry analysis. 33 Appendix A. Air and Water Releases of Recognized Carcinogens, 2004: By State Total Air Emissions Rank State (pounds) 1 TX 10,391,058 2 SC 4,194,931 3 LA 3,694,761 4 AL 3,315,804 5 FL 2,727,494 6 GA 2,688,152 7 OH 2,566,355 8 IL 2,566,470 9 IN 2,518,340 10 NC 2,433,827 11 PA 2,480,858 12 VA 2,190,876 13 TN 2,009,980 14 KY 2,061,123 15 MI 1,900,687 16 OR 1,840,414 17 IA 1,520,613 18 AR 1,386,192 19 NY 1,294,480 20 WA 1,279,089 21 MS 1,242,306 22 MO 1,183,753 23 WI 1,160,393 24 KS 1,157,103 25 MN 898,238 26 WV 822,101 Total Surface Water Emissions Total (pounds) (pounds) 228,039 10,619,097 80,853 4,275,784 154,843 3,849,604 160,998 3,476,802 57,463 2,784,957 66,862 2,755,014 45,251 2,611,606 20,958 2,587,428 66,998 2,585,338 84,283 2,518,110 33,240 2,514,098 18,162 2,209,038 121,332 2,131,312 50,395 2,111,518 25,273 1,925,960 32,839 1,873,253 22,379 1,542,992 64,273 1,450,465 72,838 1,367,318 36,475 1,315,564 14,498 1,256,804 10,361 1,194,114 15,652 1,176,045 876 1,157,979 4,606 902,844 44,742 866,843 Total Air Emissions Rank State (pounds) 27 MA 781,444 28 MT 754,276 29 CA 704,710 30 OK 730,540 31 CT 702,671 32 ME 635,527 33 NJ 433,639 34 NE 346,334 35 MD 323,033 36 AZ 219,479 37 ND 191,061 38 UT 162,708 39 ID 139,654 40 DE 139,868 41 SD 135,637 42 WY 118,931 43 HI 93,136 44 NM 81,868 45 CO 79,715 46 NH 72,256 47 RI 69,517 48 NV 17,110 49 AK 47,805 50 VT 1,914 51 DC 1 National 68,508,232 Total Surface Water Emissions Total (pounds) (pounds) 8,863 790,307 595 754,871 49,857 754,567 7,462 738,002 4,316 706,987 44,455 679,982 29,296 462,935 605 346,939 4,873 327,906 16 219,495 638 191,699 10,501 173,209 21,093 160,747 12,127 151,995 693 136,330 380 119,311 363 93,499 988 82,856 75 79,790 4,411 76,667 724 70,241 31,668 48,778 307 48,112 15 1,929 0 1 1,768,810 70,277,042 34 Appendix B. 100 U.S. Zip Codes Reporting the Most Air and Water Releases of Carcinogens, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 Zip Code 77590 29440 98632 33439 40216 35601 14652 77530 47620 79607 29706 02111 59912 77536 77541 28120 22603 70734 47112 70068 77520 97432 29115 24526 62526 52732 67210 52404 48131 70669 29461 77705 71730 38113 33440 70079 75603 19426 36752 38326 77511 61602 77507 97355 32347 70805 59802 43512 36201 77017 32837 City TEXAS CITY GEORGETOWN LONGVIEW BRYANT LOUISVILLE DECATUR ROCHESTER CHANNELVIEW MOUNT VERNON DYESS AFB CHESTER BOSTON COLUMBIA FALLS DEER PARK FREEPORT/JONES CREEK/CLUTE MOUNT HOLLY WINCHESTER GEISMAR CORYDON LA PLACE BAYTOWN DILLARD ORANGEBURG BIG ISLAND DECATUR CLINTON WICHITA CEDAR RAPIDS DUNDEE WESTLAKE MONCKS CORNER BEAUMONT/CHEEK EL DORADO MEMPHIS CLEWISTON NORCO LONGVIEW COLLEGEVILLE/TRAPPE BURKVILLE COUNCE ALVIN PEORIA PASADENA LEBANON PERRY BATON ROUGE MISSOULA DEFIANCE ANNISTON HOUSTON ORLANDO State TX SC WA FL KY AL NY TX IN TX SC MA MT TX TX NC VA LA IN LA TX OR SC VA IL IA KS IA MI LA SC TX AR TN FL LA TX PA AL TN TX IL TX OR FL LA MT OH AL TX FL Total Air and Water Emissions (pounds) 2,207,262 1,052,995 734,693 726,120 632,791 628,789 620,628 579,198 531,148 524,899 479,524 478,090 475,978 469,380 469,177 423,181 415,940 410,390 405,710 387,467 367,401 362,177 359,913 359,392 345,078 334,310 333,973 328,594 317,902 316,379 315,540 310,939 291,808 288,166 277,164 272,600 270,023 269,753 267,055 261,015 259,644 247,136 245,615 242,913 238,544 235,690 234,389 233,369 217,060 216,391 212,035 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 Zip Code 37662 29059 28716 77631 39654 75961 97478 32034 29512 37331 04740 63336 71601 36067 39832 97501 74764 77571 77978 29532 77592 50444 52761 53120 32402 37138 36769 67337 23860 31515 23851 29704 75572 42029 61350 04694 32533 31015 29406 06706 71360 71635 66115 41144 77049 28586 64119 31415 28502 City KINGSPORT HOLLY HILL CANTON ORANGE MONTICELLO NACOGDOCHES SPRINGFIELD FERNANDINA BEACH BENNETTSVILLE ETOWAH EASTON CLARKSVILLE PINE BLUFF PRATTVILLE CEDAR SPRINGS MEDFORD VALLIANT LA PORTE POINT COMFORT DARLINGTON TEXAS CITY HANLONTOWN MUSCATINE EAST TROY PANAMA CITY OLD HICKORY PINE HILL COFFEYVILLE HOPEWELL JESUP FRANKLIN CATAWBA QUEEN CITY CALVERT CITY OTTAWA BAILEYVILLE CANTONMENT CORDELE NORTH CHARLESTON WATERBURY PINEVILLE CROSSETT KANSAS CITY WURTLAND HOUSTON VANCEBORO CLAYCOMO SAVANNAH KINSTON State TN SC NC TX MS TX OR FL SC TN ME MO AR AL GA OR OK TX TX SC TX IA IA WI FL TN AL KS VA GA VA SC TX KY IL ME FL GA SC CT LA AR KS KY TX NC MO GA NC Total Air and Water Emissions (pounds) 210,265 207,060 203,139 198,030 194,941 194,721 193,830 192,863 191,925 189,532 187,909 187,863 186,674 186,339 184,139 183,916 183,402 179,227 178,691 176,465 175,471 174,402 174,052 173,357 172,662 171,278 169,793 169,006 167,458 167,414 165,938 165,133 164,122 162,614 162,415 162,206 162,133 161,017 160,748 158,823 157,302 156,263 156,219 155,954 155,620 154,898 153,981 151,997 151,164 35 Appendix C. 100 U.S. Counties Reporting the Most Air and Water Releases of Carcinogens, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 County HARRIS GALVESTON GEORGETOWN BRAZORIA JEFFERSON JEFFERSON COWLITZ PALM BEACH MORGAN MONROE MONTGOMERY ORANGEBURG POSEY TAYLOR SEDGWICK CHESTER COOK SUFFOLK FLATHEAD LINN GASTON MACON NUECES ST CHARLES ASCENSION BERKELEY FREDERICK ST JOHN THE BAPTIST SHELBY HARRISON CALCASIEU ORANGE MONROE DOUGLAS BEDFORD LINN EAST BATON ROUGE SULLIVAN NEW HAVEN CLINTON MC CURTAIN CUYAHOGA HARRISON LANE UNION NASSAU MC MINN HENDRY WAYNE LOWNDES PEORIA State TX TX SC TX TX KY WA FL AL NY PA SC IN TX KS SC IL MA MT OR NC IL TX LA LA SC VA LA TN IN LA TX MI OR VA IA LA TN CT IA OK OH TX OR AR FL TN FL MI AL IL Total Air and Water Emissions (pounds) 2,557,944 2,383,244 1,052,996 928,811 927,624 832,951 756,248 726,365 707,188 672,782 619,606 567,681 531,148 524,899 518,739 503,832 500,006 492,223 475,987 464,337 458,712 448,962 436,117 426,739 423,132 421,875 416,317 415,422 409,268 405,710 392,262 391,408 383,594 362,178 359,392 353,409 343,591 335,324 334,417 334,386 332,953 327,890 300,201 298,811 291,824 289,579 281,646 277,164 270,314 267,055 263,801 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 County HARDIN CHARLESTON AUGUSTA IBERVILLE MISSOULA TAYLOR DEFIANCE JEFFERSON BAY BERKS CALHOUN PIKE ORANGE CALHOUN ST LOUIS CHATHAM HAYWOOD AROOSTOOK DARLINGTON BIBB WALWORTH FLORENCE LAWRENCE NACOGDOCHES MARLBORO BROOKE AUTAUGA YORK OAKLAND EARLY JACKSON RICHLAND JACKSON LICKING CRAVEN MECKLENBURG ESCAMBIA WORTH DAVIDSON MUSCATINE MONROE SMITH LAKE WILCOX MONTGOMERY WYANDOTTE ALLEGHENY WAYNE RAPIDES State TN SC VA LA MT FL OH AR FL PA AL MO FL TX MO GA NC ME SC GA WI SC MS TX SC WV AL SC MI GA OR SC AL OH NC NC FL IA TN IA AL TX IN AL KS KS PA GA LA Total Air and Water Emissions (pounds) 261,015 253,915 250,654 243,905 241,714 240,438 233,371 225,560 220,304 218,255 218,066 217,123 215,491 215,014 207,017 203,599 203,139 198,609 196,063 195,529 195,473 195,241 194,948 194,721 192,071 187,866 186,339 185,875 184,441 184,139 183,916 183,889 183,291 177,763 175,768 175,456 174,614 174,402 174,062 173,273 171,459 171,331 170,571 169,793 169,032 168,619 168,150 167,414 167,322 36 Appendix D. Air and Water Releases of Recognized Developmental Toxicants, 2004: By State Total Air Emissions Rank State (pounds) 1 TN 23,549,316 2 TX 9,040,947 3 IL 6,481,819 4 IN 4,083,409 5 NC 3,752,033 6 SC 3,731,802 7 VA 3,623,611 8 LA 3,238,219 9 MS 3,182,851 10 MI 3,113,824 11 KY 2,917,524 12 PA 2,802,885 13 OH 2,524,573 14 AR 2,436,581 15 KS 2,346,709 16 NY 2,109,636 17 GA 2,056,781 18 AL 1,549,188 19 WV 1,573,354 20 MO 1,292,480 21 FL 1,199,120 22 OK 1,096,267 23 WI 1,037,768 24 IA 874,129 25 MN 746,168 26 CA 706,945 Total Surface Water Emissions Total (pounds) (pounds) 36,574 23,585,890 265,430 9,306,377 11,021 6,492,840 16,769 4,100,178 7,718 3,759,751 15,055 3,746,857 15,040 3,638,651 33,892 3,272,111 1,771 3,184,622 6,557 3,120,381 12,174 2,929,698 6,994 2,809,879 12,940 2,537,513 2,219 2,438,800 4,698 2,351,407 8,433 2,118,069 10,156 2,066,937 92,689 1,641,877 26,460 1,599,814 9,032 1,301,512 2,202 1,201,322 380 1,096,647 1,380 1,039,148 2,168 876,297 3,410 749,578 634 707,579 Total Air Emissions Rank State (pounds) 27 NJ 572,522 28 CT 530,142 29 MA 467,136 30 OR 449,738 31 NV 336,982 32 WA 338,866 33 UT 220,318 34 MD 225,541 35 NE 197,842 36 AZ 175,633 37 CO 171,688 38 NM 158,597 39 SD 156,905 40 NH 123,183 41 RI 108,911 42 ND 88,554 43 WY 86,961 44 DE 68,620 45 MT 59,139 46 AK 57,402 47 HI 31,863 48 ID 27,193 49 ME 20,682 50 VT 4,509 51 DC 0 National 95,746,866 Total Surface Water Emissions Total (pounds) (pounds) 1,682 574,204 250 530,392 178 467,314 6,054 455,792 30,017 366,999 3,930 342,796 6,783 227,101 568 226,109 112 197,954 44 175,677 26 171,714 576 159,173 693 157,598 118 123,301 33 108,944 496 89,050 20 86,981 12,364 80,984 404 59,543 235 57,637 76 31,939 706 27,899 1,457 22,139 271 4,780 0 0 672,889 96,419,755 37 Appendix E. Air and Water Releases of Recognized Reproductive Toxicants, 2004: By State Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 State TN TX IL AR KS LA WV OH NY AL PA FL MI MO IN KY VA NJ OK WI GA SC IA CA MS NC Total Air Emissions (pounds) 18,114,657 4,838,506 3,929,176 1,479,094 1,393,391 1,274,970 741,012 636,324 492,074 443,222 424,530 422,603 387,123 352,081 304,433 289,125 256,627 76,323 181,813 165,414 150,555 132,031 114,113 104,540 90,267 77,407 Total Surface Water Emissions Total (pounds) (pounds) 10,533 18,125,190 17,520 4,856,026 7,358 3,936,534 2,130 1,481,224 4,399 1,397,790 33,217 1,308,187 23,650 764,662 4,485 640,809 3,268 495,342 11,115 454,337 3,975 428,505 1,664 424,267 4,456 391,579 8,871 360,952 7,687 312,120 3,362 292,487 3,316 259,943 131,130 207,453 352 182,165 1,345 166,759 2,256 152,811 11,159 143,190 5,957 120,070 567 105,107 1,849 92,116 2,232 79,639 Total Air Emissions Rank State (pounds) 27 WA 64,670 28 UT 51,455 29 NM 47,187 30 ND 38,706 31 AK 32,674 32 MN 29,503 33 WY 32,108 34 CO 30,771 35 MT 26,015 36 AZ 21,018 37 DE 13,225 38 MD 18,042 39 MA 17,029 40 HI 16,559 41 OR 11,454 42 NE 14,151 43 ID 10,676 44 NV 7,878 45 ME 4,878 46 CT 5,567 47 RI 3,380 48 SD 2,308 49 NH 1,913 50 VT 37 51 DC 0 National 37,372,615 Total Surface Water Emissions Total (pounds) (pounds) 3,834 68,504 1,523 52,978 571 47,758 485 39,191 196 32,870 3,274 32,777 20 32,128 26 30,797 399 26,414 4 21,022 6,969 20,194 254 18,296 77 17,106 51 16,610 3,116 14,570 110 14,261 686 11,362 0 7,878 1,390 6,268 242 5,809 21 3,401 693 3,001 118 2,031 15 52 0 0 331,927 37,704,542 38 Appendix F. 100 U.S. Zip Codes Reporting the Most Air and Water Releases of Developmental Toxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 Zip Code 37778 61832 29201 37774 37055 72370 38401 28601 23228 66542 39046 48040 42134 38116 38834 77701 19310 40216 30809 61938 38024 24501 46580 79607 61054 29307 77536 74002 26055 77522 28704 14150 70669 78407 17601 77530 70805 67880 14522 76306 48131 71109 39301 35601 14043 77590 33439 28645 25401 70079 31415 City LOWLAND DANVILLE COLUMBIA LOUDON DICKSON OSCEOLA COLUMBIA HICKORY RICHMOND TECUMSEH CANTON MARYSVILLE FRANKLIN MEMPHIS CORINTH BEAUMONT ATGLEN LOUISVILLE EVANS MATTOON DYERSBURG LYNCHBURG WARSAW DYESS AFB MOUNT MORRIS SPARTANBURG DEER PARK BARNSDALL PROCTOR BAYTOWN ARDEN TONAWANDA WESTLAKE CORPUS CHRISTI LANCASTER CHANNELVIEW BATON ROUGE ULYSSES PALMYRA WICHITA FALLS DUNDEE SHREVEPORT MERIDIAN DECATUR DEPEW TEXAS CITY BRYANT LENOIR MARTINSBURG NORCO SAVANNAH State TN IL SC TN TN AR TN NC VA KS MS MI KY TN MS TX PA KY GA IL TN VA IN TX IL SC TX OK WV TX NC NY LA TX PA TX LA KS NY TX MI LA MS AL NY TX FL NC WV LA GA Total Air and Water Emissions (pounds) 14,410,790 3,555,300 2,253,649 2,226,210 1,519,851 1,428,423 1,308,483 1,144,614 1,124,656 1,116,113 1,110,539 1,094,284 1,033,212 954,972 895,066 756,449 742,827 723,266 682,072 661,122 629,456 629,241 566,923 524,904 521,541 513,944 504,156 496,660 486,973 476,802 432,667 421,923 395,369 395,232 391,949 378,191 359,392 359,006 342,388 342,221 334,271 331,230 324,461 322,615 319,367 316,387 315,560 300,114 295,000 290,464 288,510 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 Zip Code 06484 89506 77511 77017 77520 33169 70734 37091 71730 16749 79066 49093 24089 46706 45750 30901 26836 35661 75603 37642 39702 75702 79007 77642 26146 37809 70538 63336 75961 39401 47620 77507 46124 46540 40324 70776 77631 46581 37814 24526 33069 77705 78410 70043 55350 37066 44481 46947 76065 City SHELTON RENO ALVIN HOUSTON BAYTOWN MIAMI GEISMAR LEWISBURG EL DORADO SMETHPORT PAMPA THREE RIVERS FIELDALE AUBURN MARIETTA AUGUSTA MOOREFIELD MUSCLE SHOALS LONGVIEW CHURCH HILL COLUMBUS TYLER BORGER PORT ARTHUR FRIENDLY MIDWAY FRANKLIN/LOUISA CLARKSVILLE NACOGDOCHES HATTIESBURG MOUNT VERNON PASADENA EDINBURGH/CAMP ATTERBURY MIDDLEBURY GEORGETOWN SAINT GABRIEL ORANGE WARSAW MORRISTOWN BIG ISLAND POMPANO BEACH BEAUMONT/CHEEK CORPUS CHRISTI CHALMETTE HUTCHINSON GALLATIN WARREN/LORDSTOWN LOGANSPORT MIDLOTHIAN State CT NV TX TX TX FL LA TN AR PA TX MI VA IN OH GA WV AL TX TN MS TX TX TX WV TN LA MO TX MS IN TX IN IN KY LA TX IN TN VA FL TX TX LA MN TN OH IN TX Total Air and Water Emissions (pounds) 286,658 286,314 279,151 272,272 267,217 264,255 258,756 254,567 248,855 247,752 245,784 242,938 238,153 237,071 231,705 226,361 217,519 216,599 216,424 209,306 199,228 197,866 195,790 192,450 190,219 189,147 188,064 182,613 182,433 180,185 178,561 178,065 177,739 177,098 172,063 171,773 169,978 168,440 167,471 166,315 165,920 164,757 161,119 155,960 153,302 150,958 150,779 150,258 149,845 39 Appendix G. 100 U.S. Zip Codes Reporting the Most Air and Water Releases of Reproductive Toxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 Zip Code 37778 61832 37774 72370 38401 66542 79607 26055 14150 67880 77530 77536 33439 35601 79066 77511 70079 48131 70538 77017 77590 24526 77631 79007 77520 44035 63336 77541 08023 77642 77705 26184 75702 79720 77651 75603 70805 77463 77507 78410 70586 77522 70669 70710 77640 33440 15025 77630 52732 40353 43402 City LOWLAND DANVILLE LOUDON OSCEOLA COLUMBIA TECUMSEH DYESS AFB PROCTOR TONAWANDA ULYSSES CHANNELVIEW DEER PARK BRYANT DECATUR PAMPA ALVIN NORCO DUNDEE FRANKLIN/LOUISA HOUSTON TEXAS CITY BIG ISLAND ORANGE BORGER BAYTOWN ELYRIA CLARKSVILLE FREEPORT/JONES CREEK/CLUTE DEEPWATER PORT ARTHUR BEAUMONT/CHEEK WAVERLY TYLER BIG SPRING PORT NECHES LONGVIEW BATON ROUGE OLD OCEAN PASADENA CORPUS CHRISTI VILLE PLATTE BAYTOWN WESTLAKE ADDIS PORT ARTHUR CLEWISTON CLAIRTON/JEFFERSON HILLS ORANGE CLINTON MOUNT STERLING BOWLING GREEN State TN IL TN AR TN KS TX WV NY KS TX TX FL AL TX TX LA MI LA TX TX VA TX TX TX OH MO TX NJ TX TX WV TX TX TX TX LA TX TX TX LA TX LA LA TX FL PA TX IA KY OH Total Air and Water Emissions (pounds) 14,410,776 3,555,300 2,226,209 1,428,423 1,308,478 951,849 524,899 486,973 416,892 359,006 340,276 323,715 288,050 274,209 245,776 239,873 239,052 231,924 188,064 187,996 172,488 166,292 162,676 159,513 145,925 144,302 141,293 137,882 136,096 132,164 122,336 120,240 113,802 112,847 106,867 105,909 102,261 102,110 101,420 98,534 95,363 91,496 90,228 89,947 89,336 88,782 88,382 82,068 80,803 77,250 77,065 Rank 52 53 54 55 56 57 58 59 60 61 Zip Code 77641 46304 78403 26037 44004 78407 65440 40216 70734 54981 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 19061 46402 76065 37138 77701 70037 63629 70043 63048 39581 23692 19145 61350 77506 62084 53044 47586 25112 36505 43512 44481 61537 77503 75706 74501 77592 70721 78071 77978 77632 49707 61846 42029 29492 74820 70765 70057 79008 45714 City PORT ARTHUR CHESTERTON/BURNS HARBOR CORPUS CHRISTI FOLLANSBEE ASHTABULA CORPUS CHRISTI BOSS LOUISVILLE GEISMAR WAUPACA MARCUS HOOK/TRAINER/ LINWOOD GARY MIDLOTHIAN OLD HICKORY BEAUMONT BELLE CHASSE BUNKER CHALMETTE HERCULANEUM PASCAGOULA YORKTOWN/GRAFTON PHILADELPHIA OTTAWA PASADENA ROXANA KOHLER TELL CITY INSTITUTE AXIS DEFIANCE WARREN/LORDSTOWN HENRY PASADENA TYLER MC ALESTER TEXAS CITY CARVILLE THREE RIVERS POINT COMFORT ORANGE ALPENA GEORGETOWN CALVERT CITY WANDO ADA PLAQUEMINE HAHNVILLE/TAFT BORGER BELPRE State TX IN TX WV OH TX MO KY LA WI PA IN TX TN TX LA MO LA MO MS VA PA IL TX IL WI IN WV AL OH OH IL TX TX OK TX LA TX TX TX MI IL KY SC OK LA LA TX OH Total Air and Water Emissions (pounds) 76,695 73,666 72,304 71,148 70,213 66,864 66,138 65,363 65,273 62,592 61,793 60,585 59,870 59,829 59,010 58,883 53,893 53,625 53,045 51,902 51,602 51,234 50,665 49,738 49,590 49,527 49,400 48,891 47,509 46,588 45,435 43,214 42,794 42,746 42,680 42,631 41,252 41,119 39,685 39,634 38,598 38,211 34,471 34,450 34,426 34,249 34,143 33,712 32,215 40 Appendix H. 100 U.S. Counties Reporting the Most Air and Water Releases of Developmental Toxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 County HAMBLEN VERMILION HARRIS RICHLAND LOUDON DICKSON MISSISSIPPI JEFFERSON MAURY CATAWBA SHELBY HENRICO SHAWNEE MADISON ST CLAIR SIMPSON ALCORN JEFFERSON ERIE CHESTER NUECES KOSCIUSKO COLUMBIA SPARTANBURG LYNCHBURG CITY COLES DYER ELKHART BRAZORIA HENRY OGLE TAYLOR MARSHALL OSAGE BUNCOMBE CALCASIEU LANCASTER GALVESTON EAST BATON ROUGE MONROE ST CHARLES CALDWELL LOS ANGELES CADDO DALLAS GRANT COOK LAUDERDALE WICHITA WAYNE MORGAN State TN IL TX SC TN TN AR TX TN NC TN VA KS MS MI KY MS KY NY PA TX IN GA SC VA IL TN IN TX VA IL TX WV OK NC LA PA TX LA MI LA NC CA LA TX KS IL MS TX NY AL Total Air and Water Emissions (pounds) 14,578,261 3,621,127 2,346,750 2,258,044 2,226,212 1,519,851 1,430,888 1,390,937 1,335,292 1,174,320 1,159,282 1,124,715 1,116,124 1,110,679 1,098,133 1,033,212 895,066 839,206 830,597 797,278 738,796 735,407 682,072 678,668 670,790 661,122 631,927 629,711 574,340 529,633 528,013 524,904 497,177 496,660 433,528 433,231 425,852 410,072 391,265 384,420 379,881 377,677 374,179 367,454 366,908 359,006 356,175 348,064 344,479 342,403 326,618 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 County MC KEAN ORANGE IBERVILLE PALM BEACH HUTCHINSON FAIRFIELD CHATHAM BERKELEY DE KALB WASHOE MIAMI-DADE WASHINGTON HARRISON ALLEGHENY ASCENSION MARSHALL UNION GRAY COLBERT MIDDLESEX ST JOSEPH SMITH RICHMOND WAYNE HARDY LOWNDES GREENE HAWKINS MIDDLESEX ST MARY JOHNSON GASTON NEWPORT NEWS CITY TYLER BROWARD MARION PIKE NACOGDOCHES FORREST TRUMBULL POSEY ALLEN ST BERNARD OAKLAND KENT YORK PLEASANTS SEDGWICK SCOTT State PA TX LA FL TX CT GA WV IN NV FL OH TX PA LA TN AR TX AL NJ MI TX GA MI WV MS TN TN MA LA IN NC VA WV FL IN MO TX MS OH IN OH LA MI MI PA WV KS KY Total Air and Water Emissions (pounds) 326,530 326,003 316,878 315,798 313,126 305,736 296,332 295,001 288,441 286,672 282,318 268,326 265,893 265,350 258,760 254,567 248,871 246,237 246,005 244,842 242,965 240,659 228,695 225,082 217,519 214,311 211,741 210,293 208,670 206,417 200,097 197,959 190,777 190,219 185,976 184,481 182,673 182,433 180,316 179,732 178,561 176,501 176,368 175,492 174,807 173,821 172,281 172,143 172,063 41 Appendix I. 100 U.S. Counties Reporting the Most Air and Water Releases of Reproductive Toxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 County HAMBLEN VERMILION LOUDON MISSISSIPPI HARRIS MAURY SHAWNEE JEFFERSON TAYLOR MARSHALL BRAZORIA ERIE GRANT ST CHARLES PALM BEACH ORANGE MORGAN NUECES GRAY MONROE GALVESTON ST MARY HUTCHINSON BEDFORD SMITH LORAIN PIKE SALEM CALCASIEU PLEASANTS EAST BATON ROUGE ALLEGHENY HOWARD HARRISON WEST BATON ROUGE EVANGELINE HENDRY IBERVILLE JEFFERSON LAKE MADISON CLINTON WOOD MONTGOMERY PORTER BROOKE ASHTABULA IRON ASCENSION DELAWARE REYNOLDS State TN IL TN AR TX TN KS TX TX WV TX NY KS LA FL TX AL TX TX MI TX LA TX VA TX OH MO NJ LA WV LA PA TX TX LA LA FL LA KY IN IL IA OH KY IN WV OH MO LA PA MO Total Air and Water Emissions (pounds) 14,410,776 3,593,888 2,226,211 1,429,962 1,351,884 1,309,932 951,860 588,806 524,899 494,578 489,610 422,397 359,006 297,427 288,288 285,062 274,651 253,922 246,229 233,019 215,374 206,417 193,225 166,292 156,549 148,553 141,343 136,154 124,039 120,637 120,473 117,034 112,847 106,413 105,225 95,363 88,782 87,815 87,807 84,995 80,998 80,863 77,441 77,250 74,577 71,149 70,236 66,138 65,276 63,999 63,266 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 County WAUPACA ST BERNARD ELLIS DAVIDSON PLAQUEMINES MOBILE LOS ANGELES WAYNE JEFFERSON JACKSON PHILADELPHIA YORK TRUMBULL LA SALLE CALHOUN KANAWHA SHEBOYGAN PERRY DEFIANCE BOYD MARSHALL PITTSBURG WILL LIVE OAK JEFFERSON BERKELEY RICHMOND ALPENA GLOUCESTER WASHINGTON MARSHALL PONTOTOC MARION LUCAS SALT LAKE MORTON VICTORIA MC MINN CUYAHOGA ST LAWRENCE ORANGEBURG MARINETTE KAY BUTLER MOORE ST JOHN THE BAPTIST SULLIVAN TULSA BARTOW State WI LA TX TN LA AL CA MI MO MS PA VA OH IL TX WV WI IN OH KY IL OK IL TX AL SC GA MI NJ OH KY OK IN OH UT ND TX TN OH NY SC WI OK PA TX LA TN OK GA Total Air and Water Emissions (pounds) 62,594 62,181 60,326 60,115 58,944 54,889 54,292 53,775 53,774 52,013 51,718 51,602 51,410 51,243 50,506 50,274 49,973 49,400 46,590 45,879 43,214 42,680 41,375 41,119 40,678 39,844 39,552 38,598 35,005 34,813 34,475 34,426 33,281 32,807 31,396 30,780 30,406 29,641 29,345 28,883 28,380 28,320 28,235 28,078 27,868 27,645 26,889 26,634 25,714 42 Appendix J. Air and Water Releases of Suspected Neurotoxicants, 2004: By State Total Air Emissions Rank State (pounds) 1 TX 73,076,723 2 TN 52,011,756 3 GA 45,646,927 4 LA 45,916,257 5 OH 42,767,562 6 SC 32,887,312 7 AL 34,264,640 8 NC 34,217,139 9 IL 32,715,557 10 IN 30,352,468 11 FL 26,649,428 12 VA 26,376,235 13 MS 23,525,548 14 IA 22,575,345 15 KY 22,098,060 16 PA 21,741,816 17 MI 21,158,834 18 AR 19,702,941 19 MO 20,098,727 20 CA 15,735,587 21 OK 14,212,450 22 WI 13,185,508 23 OR 11,919,902 24 WV 10,416,257 25 MN 10,797,724 26 KS 10,953,359 Total Surface Water Emissions (pounds) 3,140,585 1,405,162 1,787,607 1,464,655 648,169 6,213,447 2,102,890 635,978 258,542 1,151,159 422,014 376,671 448,052 228,570 423,410 360,496 356,347 814,476 126,826 2,219,661 186,700 310,407 347,205 930,043 285,403 8,637 Total (pounds) 76,217,308 53,416,918 47,434,534 47,380,912 43,415,731 39,100,759 36,367,530 34,853,117 32,974,099 31,503,627 27,071,442 26,752,906 23,973,600 22,803,915 22,521,470 22,102,312 21,515,181 20,517,417 20,225,553 17,955,248 14,399,150 13,495,915 12,267,107 11,346,300 11,083,127 10,961,996 Total Air Emissions Rank State (pounds) 27 WA 9,113,976 28 NY 9,489,542 29 NE 8,983,004 30 MD 6,839,745 31 UT 6,124,502 32 ME 4,748,872 33 NJ 4,546,557 34 ID 4,096,123 35 MT 3,731,916 36 MA 2,798,158 37 AZ 2,696,188 38 ND 2,301,737 39 CO 2,226,283 40 CT 2,052,690 41 DE 1,767,071 42 AK 1,521,671 43 WY 1,658,781 44 SD 1,645,134 45 NV 1,248,969 46 NH 1,209,026 47 NM 763,228 48 RI 422,666 49 HI 309,039 50 VT 49,075 51 DC 3,428 National 795,351,443 Total Surface Water Emissions Total (pounds) (pounds) 1,285,960 10,399,936 358,998 9,848,540 45,569 9,028,573 155,065 6,994,810 12,113 6,136,615 683,953 5,432,825 463,640 5,010,197 310,176 4,406,299 41,844 3,773,760 10,611 2,808,769 6,281 2,702,469 31,721 2,333,458 33,592 2,259,875 49,072 2,101,762 243,377 2,010,448 354,468 1,876,139 4,928 1,663,709 899 1,646,033 45,940 1,294,909 75,766 1,284,792 3,063 766,291 1,676 424,342 1,477 310,516 5,323 54,398 5,742 9,170 30,884,366 826,235,809 43 Appendix K. 100 U.S. Zip Codes Reporting the Most Air and Water Releases of Suspected Neurotoxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 Zip Code 37778 77590 44004 70346 51054 29445 68310 71052 28456 30901 71601 61832 75572 84029 31515 29506 70805 23860 63937 62526 24426 74019 98632 30165 29440 36470 39815 42029 35601 45802 23851 33830 54494 73701 37134 30906 70734 75603 32034 21226 37774 52732 52627 77541 40216 36426 95564 43512 32533 37662 74764 City LOWLAND TEXAS CITY ASHTABULA DONALDSONVILLE SERGEANT BLUFF MOUNT HOLLY/GOOSE CREEK BEATRICE MANSFIELD RIEGELWOOD AUGUSTA PINE BLUFF DANVILLE QUEEN CITY GRANTSVILLE/ROWLEY JESUP FLORENCE BATON ROUGE HOPEWELL ELLSINORE DECATUR COVINGTON CLAREMORE LONGVIEW ROME GEORGETOWN PERDUE HILL ATTAPULGUS CALVERT CITY DECATUR LIMA FRANKLIN BARTOW WISCONSIN RAPIDS ENID NEW JOHNSONVILLE AUGUSTA GEISMAR LONGVIEW FERNANDINA BEACH BALTIMORE/CURTIS BAY LOUDON CLINTON FORT MADISON FREEPORT/JONES CREEK/CLUTE LOUISVILLE BREWTON SAMOA DEFIANCE CANTONMENT KINGSPORT VALLIANT State TN TX OH LA IA SC NE LA NC GA AR IL TX UT GA SC LA VA MO IL VA OK WA GA SC AL GA KY AL OH VA FL WI OK TN GA LA TX FL MD TN IA IA TX KY AL CA OH FL TN OK Total Air and Water Emissions (pounds) 14,463,493 7,292,059 6,952,997 6,935,633 6,791,533 6,245,054 4,881,133 4,748,082 4,703,218 4,655,458 4,610,770 4,397,460 4,372,316 4,034,429 3,863,929 3,693,281 3,576,343 3,515,808 3,431,376 3,414,179 3,331,000 3,287,303 3,265,304 3,218,901 3,133,189 3,100,885 3,067,885 2,993,683 2,805,774 2,785,622 2,776,052 2,761,564 2,753,216 2,727,855 2,709,669 2,683,454 2,637,720 2,609,001 2,579,715 2,568,219 2,564,318 2,535,187 2,507,954 2,505,716 2,456,796 2,391,290 2,348,917 2,331,652 2,323,288 2,318,152 2,302,263 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 Zip Code 29201 28716 39654 70669 39832 29406 38310 45750 31601 71220 67801 77571 32177 77701 94553 39046 28586 70663 77520 77705 31415 47629 70634 47620 97051 77536 70086 38326 36769 64119 37167 48131 39462 77631 32402 71630 70427 59802 39156 23181 32347 39567 71901 36851 99611 61025 37055 35618 77530 City COLUMBIA CANTON MONTICELLO WESTLAKE CEDAR SPRINGS NORTH CHARLESTON ADAMSVILLE MARIETTA VALDOSTA/CLYATTVILLE BASTROP DODGE CITY LA PORTE PALATKA BEAUMONT MARTINEZ CANTON VANCEBORO SULPHUR BAYTOWN BEAUMONT/CHEEK SAVANNAH NEWBURGH DERIDDER MOUNT VERNON SAINT HELENS DEER PARK SAINT JAMES COUNCE PINE HILL CLAYCOMO SMYRNA DUNDEE NEW AUGUSTA ORANGE PANAMA CITY ARKANSAS CITY BOGALUSA MISSOULA REDWOOD WEST POINT PERRY PASCAGOULA HOT SPRINGS COTTONTON KENAI EAST DUBUQUE DICKSON COURTLAND CHANNELVIEW State SC NC MS LA GA SC TN OH GA LA KS TX FL TX CA MS NC LA TX TX GA IN LA IN OR TX LA TN AL MO TN MI MS TX FL AR LA MT MS VA FL MS AR AL AK IL TN AL TX Total Air and Water Emissions (pounds) 2,294,687 2,293,821 2,280,176 2,264,804 2,246,508 2,208,562 2,165,621 2,138,718 2,108,395 2,095,065 2,036,197 2,013,412 1,986,585 1,954,379 1,954,368 1,949,833 1,942,771 1,871,955 1,870,940 1,867,002 1,856,978 1,841,409 1,825,145 1,814,407 1,791,479 1,785,563 1,773,454 1,748,763 1,746,748 1,726,556 1,723,727 1,705,956 1,704,484 1,701,442 1,689,517 1,683,659 1,682,233 1,666,297 1,664,143 1,662,242 1,653,319 1,646,127 1,637,897 1,629,605 1,622,968 1,616,863 1,590,981 1,585,653 1,575,443 44 Appendix L. 100 U.S. Counties Reporting the Most Air and Water Releases of Suspected Neurotoxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 County HAMBLEN HARRIS ASCENSION GALVESTON BERKELEY RICHMOND ASHTABULA JEFFERSON WOODBURY LOS ANGELES JEFFERSON HUMPHREYS GAGE EAST BATON ROUGE VERMILION COLUMBUS DE SOTO CALCASIEU JEFFERSON SHELBY CASS BRAZORIA POLK TOOELE ORANGE RICHLAND ELKHART FLORENCE WAYNE COOK MORGAN WOOD MACON CHATHAM HOPEWELL CITY FLOYD ALLEN CARTER ROGERS COWLITZ WAYNE NASSAU COVINGTON CITY MONROE JACKSON GEORGETOWN BALTIMORE CITY WASHINGTON DECATUR SULLIVAN MARSHALL State TN TX LA TX SC GA OH TX IA CA AR TN NE LA IL NC LA LA KY TN TX TX FL UT TX SC IN SC GA IL AL WI IL GA VA GA OH MO OK WA MI FL VA AL MS SC MD OH GA TN KY Total Air and Water Emissions (pounds) 14,702,488 14,231,090 9,705,246 8,717,524 7,506,926 7,339,191 7,142,731 7,089,354 7,037,963 5,214,571 5,102,041 4,986,947 4,881,133 4,861,928 4,823,500 4,782,051 4,775,248 4,771,396 4,747,848 4,585,412 4,372,328 4,179,426 4,078,549 4,034,763 4,024,714 3,971,167 3,938,970 3,933,525 3,880,219 3,830,120 3,806,697 3,662,266 3,612,334 3,546,361 3,515,693 3,457,199 3,442,179 3,431,376 3,430,701 3,379,981 3,357,501 3,352,735 3,331,000 3,282,036 3,255,259 3,133,190 3,097,865 3,091,327 3,072,332 3,071,909 2,993,687 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 County HARRISON MONROE ISLE OF WIGHT ESCAMBIA CHARLESTON CONTRA COSTA GARFIELD JEFFERSON LEE LOUDON MC CURTAIN CLINTON CALHOUN LICKING HUMBOLDT ALLEGHENY ESCAMBIA CALHOUN BAY DEFIANCE IBERVILLE NUECES ST CHARLES COLBERT HAYWOOD LAWRENCE CATAWBA WARREN EARLY UNION MCNAIRY LOWNDES MISSISSIPPI RUSSELL LOWNDES MOREHOUSE CRAVEN ST JAMES PUTNAM HARDIN FORD GLYNN OAKLAND RUTHERFORD LINN MADISON YORK LANE HARRISON State TX MI VA FL SC CA OK AL IA TN OK IA TX OH CA PA AL SC FL OH LA TX LA AL NC MS NC MS GA OH TN MS AR AL GA LA NC LA FL TN KS GA MI TN OR MS SC OR MS Total Air and Water Emissions (pounds) 2,963,472 2,878,742 2,791,898 2,781,263 2,767,853 2,756,035 2,727,855 2,677,091 2,644,610 2,607,810 2,591,461 2,535,995 2,529,941 2,525,779 2,443,450 2,425,943 2,391,370 2,380,599 2,344,763 2,331,654 2,312,425 2,308,806 2,304,927 2,297,691 2,293,821 2,280,183 2,277,971 2,250,995 2,246,508 2,208,025 2,165,621 2,133,077 2,115,759 2,110,570 2,108,755 2,095,065 2,087,418 2,070,525 2,041,371 2,040,707 2,036,197 2,022,030 2,004,906 1,988,825 1,981,562 1,953,806 1,934,243 1,933,688 1,916,664 45 Appendix M. Air Releases of Suspected Respiratory Toxicants, 2004: By State Rank State 1 OH 2 NC 3 TN 4 TX 5 PA 6 GA 7 FL 8 IN 9 WV 10 KY 11 SC 12 LA 13 IL 14 AL 15 MI 16 VA 17 MD 18 MS 19 IA 20 MO 21 NY 22 AR 23 WI 24 CA 25 OK 26 OR Total Air Emissions (pounds) 116,946,061 99,151,657 90,886,174 89,551,196 86,166,871 86,018,217 71,732,901 69,213,183 67,462,213 58,201,781 53,833,882 51,726,808 51,390,003 51,017,194 47,385,163 45,911,573 32,647,236 31,295,706 27,638,474 25,389,668 22,100,072 21,611,950 19,078,998 17,207,357 15,431,081 12,499,164 Total Air Emissions Rank State (pounds) 27 KS 12,256,702 28 MN 11,898,443 29 WA 11,712,062 30 NJ 11,435,560 31 NE 10,520,352 32 UT 9,682,475 33 DE 7,540,269 34 MA 5,911,189 35 ME 5,394,464 36 ND 4,546,642 37 NH 4,531,690 38 ID 4,296,733 39 MT 4,250,357 40 AZ 4,248,933 41 CO 2,862,040 42 HI 2,343,006 43 WY 2,263,701 44 CT 2,259,767 45 NV 1,742,951 46 SD 1,704,384 47 AK 1,630,231 48 NM 984,354 49 RI 418,133 50 VT 50,727 51 DC 3,429 National 1,485,983,177 46 Appendix N. 100 U.S. Zip Codes Reporting the Most Air Releases of Suspected Respiratory Toxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 Zip Code 37134 15774 25213 30120 37778 26041 27009 28682 45144 25265 27343 34428 21226 43961 30170 43913 37050 45620 47670 31061 45715 48161 77590 51054 32514 41045 15461 70346 15748 20664 28012 41230 45052 42337 26541 29440 43811 32409 32177 47629 37748 17821 17370 29044 84029 15944 30165 71052 39735 28456 68310 City NEW JOHNSONVILLE SHELOCTA WINFIELD CARTERSVILLE LOWLAND MOUNDSVILLE BELEWS CREEK TERRELL MANCHESTER NEW HAVEN SEMORA CRYSTAL RIVER BALTIMORE/CURTIS BAY STRATTON ROOPVILLE BRILLIANT CUMBERLAND CITY CHESHIRE PRINCETON MILLEDGEVILLE BEVERLY MONROE TEXAS CITY SERGEANT BLUFF PENSACOLA GHENT MASONTOWN DONALDSONVILLE HOMER CITY NEWBURG BELMONT LOUISA NORTH BEND DRAKESBORO MAIDSVILLE/EVERETTVILLE GEORGETOWN CONESVILLE SOUTHPORT PALATKA NEWBURGH HARRIMAN DANVILLE YORK HAVEN EASTOVER GRANTSVILLE/ROWLEY NEW FLORENCE ROME MANSFIELD ACKERMAN RIEGELWOOD BEATRICE State TN PA WV GA TN WV NC NC OH WV NC FL MD OH GA OH TN OH IN GA OH MI TX IA FL KY PA LA PA MD NC KY OH KY WV SC OH FL FL IN TN PA PA SC UT PA GA LA MS NC NE Total Air Emissions (pounds) 17,185,681 16,403,890 15,708,386 15,476,036 14,769,926 14,312,502 13,661,597 13,571,617 12,977,392 12,526,073 12,160,544 11,960,774 11,817,842 11,729,787 10,377,850 10,049,602 9,984,805 9,474,147 8,679,874 8,678,131 8,638,437 7,531,571 7,460,286 7,247,509 7,025,872 7,011,109 6,869,976 6,847,847 6,721,953 6,480,304 6,279,138 6,278,862 6,278,293 6,137,785 6,105,916 6,024,390 5,875,052 5,851,790 5,831,584 5,728,528 5,706,867 5,645,152 5,574,143 5,440,215 5,248,250 5,219,545 5,201,216 5,082,654 5,036,140 4,923,318 4,895,989 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 Zip Code 45157 23836 30901 71601 20608 61832 62017 41056 75572 32226 70805 49460 24426 29506 27574 23860 47025 35186 62526 19966 42348 28401 47928 20842 07306 31515 35601 28114 63937 98632 37716 37662 23851 44095 29445 47150 47250 74019 35580 32034 52732 45750 75603 16201 39815 42029 40330 16873 15144 City NEW RICHMOND CHESTER AUGUSTA PINE BLUFF AQUASCO DANVILLE COFFEEN MAYSVILLE QUEEN CITY JACKSONVILLE BATON ROUGE WEST OLIVE COVINGTON FLORENCE ROXBORO HOPEWELL LAWRENCEBURG/GREENDALE WILSONVILLE DECATUR MILLSBORO HAWESVILLE WILMINGTON CAYUGA DICKERSON JERSEY CITY JESUP DECATUR MOORESBORO ELLSINORE LONGVIEW CLINTON KINGSPORT FRANKLIN EASTLAKE MOUNT HOLLY/GOOSE CREEK NEW ALBANY MADISON CLAREMORE PARRISH FERNANDINA BEACH CLINTON MARIETTA LONGVIEW KITTANNING ATTAPULGUS CALVERT CITY HARRODSBURG SHAWVILLE SPRINGDALE State OH VA GA AR MD IL IL KY TX FL LA MI VA SC NC VA IN AL IL DE KY NC IN MD NJ GA AL NC MO WA TN TN VA OH SC IN IN OK AL FL IA OH TX PA GA KY KY PA PA Total Air Emissions (pounds) 4,870,835 4,785,337 4,663,723 4,563,572 4,547,584 4,515,033 4,511,880 4,454,679 4,453,511 4,390,622 4,346,953 4,300,126 4,185,458 4,117,400 4,112,488 4,064,790 3,965,792 3,959,130 3,921,676 3,918,683 3,898,896 3,831,483 3,794,973 3,661,598 3,623,418 3,615,935 3,578,071 3,560,855 3,431,376 3,407,948 3,401,043 3,392,628 3,352,926 3,343,537 3,342,639 3,325,634 3,288,579 3,276,081 3,235,443 3,220,527 3,182,220 3,134,628 3,125,469 3,110,625 3,059,576 3,057,576 3,051,986 2,989,270 2,985,206 47 Appendix O. 100 U.S. Counties Reporting the Most Air Releases of Suspected Respiratory Toxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 County JEFFERSON ARMSTRONG HUMPHREYS HARRIS PERSON MARSHALL PUTNAM BARTOW CATAWBA HAMBLEN STOKES ADAMS MASON BALTIMORE CITY CITRUS INDIANA WASHINGTON MONROE HEARD STEWART ASCENSION GALLIA ESCAMBIA GALVESTON GASTON GIBSON PUTNAM BAY JEFFERSON WOODBURY RICHLAND YORK HAMILTON RICHMOND CARROLL SHELBY BERKELEY WAYNE GREENE DUVAL MUHLENBERG CHARLES JEFFERSON COSHOCTON LAWRENCE MONONGALIA GEORGETOWN VERMILION WARRICK PUTNAM CLERMONT State OH PA TN TX NC WV WV GA NC TN NC OH WV MD FL PA OH MI GA TN LA OH FL TX NC IN GA FL TX IA SC PA OH GA KY TN SC MI PA FL KY MD KY OH KY WV SC IL IN FL OH Total Air Emissions (pounds) 21,850,211 19,514,515 18,805,656 17,672,267 16,396,477 16,017,366 15,716,564 15,660,124 15,016,129 15,009,961 13,664,898 12,977,392 12,659,702 12,349,782 12,127,099 11,941,498 11,931,256 11,604,377 10,377,850 9,984,805 9,573,764 9,474,647 9,260,540 9,229,221 8,874,420 8,683,717 8,563,051 8,377,691 8,112,647 7,889,087 7,875,688 7,467,192 7,360,347 7,320,454 7,097,269 7,032,506 7,002,088 6,984,390 6,924,640 6,858,221 6,512,853 6,481,930 6,316,384 6,292,872 6,278,862 6,116,646 6,024,714 5,961,837 5,917,853 5,886,370 5,815,137 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 County ROANE CHESTERFIELD MONTOUR EAST BATON ROUGE FLOYD CALCASIEU ALLEGHENY JEFFERSON TOOELE COOK LOS ANGELES DE SOTO OTTAWA CHOCTAW POLK COLUMBUS GAGE MORGAN PRINCE GEORGES MONTGOMERY MASON CASS BRAZORIA FLORENCE SHELBY MACON SUSSEX DEARBORN LAKE COVINGTON CITY MONROE PEORIA SULLIVAN WOOD VERMILLION HOPEWELL CITY NEW HANOVER JACKSON HANCOCK NASSAU ELKHART COLBERT HARRISON NORTHAMPTON ALLEN HUDSON ORANGE RUTHERFORD MONTGOMERY State TN VA PA LA GA LA PA AR UT IL CA LA MI MS FL NC NE AL MD IL KY TX TX SC AL IL DE IN OH VA NY IL TN WI IN VA NC MS KY FL IN AL TX PA OH NJ TX NC MD Total Air Emissions (pounds) 5,712,127 5,709,240 5,645,152 5,616,248 5,449,363 5,405,489 5,402,060 5,253,925 5,249,077 5,241,848 5,190,933 5,109,771 5,063,441 5,036,140 5,002,297 5,002,094 4,895,989 4,602,863 4,551,892 4,518,941 4,454,679 4,453,511 4,449,368 4,345,535 4,333,556 4,296,072 4,289,294 4,258,237 4,218,884 4,185,458 4,144,575 4,141,500 4,126,108 4,116,611 4,076,443 4,063,817 4,029,927 4,006,943 3,945,329 3,944,962 3,944,696 3,810,572 3,809,877 3,790,383 3,693,514 3,686,974 3,674,062 3,664,226 3,662,099 48 Appendix P. Air and Water Releases of Dioxins, 2004: By State Total Air Emissions Rank State (grams) 1 TX 87.44 2 LA 49.46 3 AL 42.05 4 NH 153.79 5 AR 26.76 6 KS 69.19 7 FL 58.86 8 IN 60.97 9 MS 13.50 10 PA 49.91 11 IL 43.48 12 TN 32.36 13 OH 39.61 14 KY 35.86 15 NY 30.32 16 MO 30.31 17 NJ 31.64 18 SC 29.16 19 VA 27.17 20 GA 24.52 21 WI 28.84 22 WV 13.97 23 NC 21.94 24 WA 15.80 25 CA 16.37 26 MI 16.13 Total Surface Water Emissions Total (grams) (grams) 751.81 839.24 365.28 414.74 124.19 166.24 0.00 153.79 53.55 80.31 0.00 69.19 3.29 62.15 0.02 60.99 46.47 59.97 0.91 50.82 0.04 43.52 8.32 40.68 0.42 40.03 0.02 35.89 4.64 34.96 3.15 33.46 0.18 31.82 1.28 30.44 2.28 29.45 4.63 29.14 0.05 28.89 14.25 28.21 2.69 24.63 8.33 24.13 1.55 17.92 1.57 17.70 Total Air Emissions Rank State (grams) 27 IA 17.05 28 MD 15.86 29 AZ 13.34 30 MA 13.09 31 UT 11.69 32 NV 9.84 33 OK 9.18 34 WY 9.44 35 OR 8.24 36 MN 8.74 37 AK 8.18 38 ME 7.15 39 ND 7.02 40 MT 5.67 41 CO 5.54 42 SD 5.52 43 CT 5.44 44 ID 1.06 45 DE 4.25 46 HI 4.39 47 NM 2.96 48 NE 2.53 49 DC 0.00 49 RI 0.00 49 VT 0.00 National 1,225.59 Total Surface Water Emissions (grams) 0.00 0.22 0.00 0.17 0.00 0.00 0.28 0.00 0.68 0.00 0.00 0.99 0.00 0.00 0.04 0.00 0.06 4.18 0.32 0.00 0.00 0.00 0.00 0.00 0.00 1,405.84 Total (grams) 17.05 16.08 13.34 13.26 11.69 9.84 9.46 9.44 8.92 8.74 8.18 8.14 7.02 5.67 5.57 5.52 5.50 5.24 4.57 4.39 2.96 2.53 0.00 0.00 0.00 2,631.43 49 Appendix Q. 100 U.S. Zip Codes Reporting the Most Air and Water Releases of Dioxins, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 Zip Code 77541 70765 77571 03576 35035 67215 71822 70669 38960 36543 70057 08862 46304 70805 26155 29448 78112 46402 77015 62539 54603 36427 71635 99752 14652 08871 71601 39577 32226 37134 46312 17929 77536 60450 23692 32177 36610 36916 61021 65440 85938 11768 44446 83501 78012 36079 34956 71730 02726 21703 37662 City FREEPORT PLAQUEMINE LA PORTE DIXVILLE NOTCH BRIERFIELD WICHITA ASHDOWN WESTLAKE GRENADA HUXFORD HAHNVILLE PERTH AMBOY CHESTERTON/BURNS HARBOR BATON ROUGE NEW MARTINSVILLE HARLEYVILLE ELMENDORF GARY HOUSTON ILLIOPOLIS LA CROSSE BREWTON CROSSETT KOTZEBUE ROCHESTER SAYREVILLE PINE BLUFF WIGGINS JACKSONVILLE NEW JOHNSONVILLE EAST CHICAGO CRESSONA DEER PARK MORRIS YORKTOWN/GRAFTON PALATKA MOBILE PENNINGTON DIXON BOSS SPRINGERVILLE NORTHPORT NILES LEWISTON CHRISTINE TROY INDIANTOWN EL DORADO SOMERSET FREDERICK KINGSPORT State TX LA TX NH AL KS AR LA MS AL LA NJ IN LA WV SC TX IN TX IL WI AL AR AK NY NJ AR MS FL TN IN PA TX IL VA FL AL AL IL MO AZ NY OH ID TX AL FL AR MA MD TN Total Air and Water Emissions (grams) 525.37 298.47 239.37 151.27 74.97 57.01 43.77 43.24 36.77 27.85 22.00 19.00 17.80 17.00 15.10 11.46 9.29 8.63 8.42 8.30 8.07 7.93 7.67 7.53 7.13 7.00 6.80 6.56 6.54 6.50 6.39 6.00 5.94 5.85 5.59 5.34 5.33 5.20 5.11 5.00 4.94 4.90 4.80 4.78 4.67 4.63 4.57 4.47 4.44 4.39 4.29 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 80 82 83 84 85 86 87 87 87 90 91 92 93 94 95 96 97 98 98 100 Zip Code 71836 98106 70791 75572 34219 23004 59323 37660 75074 37050 70734 52761 62217 15077 23851 63336 43512 27107 82201 36769 71360 29440 32831 57702 34691 84078 24175 36426 84029 98632 39358 12550 85654 33316 97818 63866 11101 78359 14012 66536 02563 21226 70764 71052 30901 45620 42337 27343 34428 City FOREMAN SEATTLE ZACHARY QUEEN CITY PARRISH ARVONIA COLSTRIP KINGSPORT PLANO CUMBERLAND CITY GEISMAR MUSCATINE BALDWIN SHIPPINGPORT FRANKLIN CLARKSVILLE DEFIANCE WINSTON-SALEM WHEATLAND PINE HILL PINEVILLE GEORGETOWN ORLANDO RAPID CITY HOLIDAY VERNAL TROUTVILLE BREWTON GRANTSVILLE/ROWLEY LONGVIEW SCOOBA NEWBURGH RILLITO FORT LAUDERDALE BOARDMAN MARSTON LONG ISLAND CITY GREGORY BARKER SAINT MARYS SANDWICH BALTIMORE PLAQUEMINE MANSFIELD AUGUSTA CHESHIRE DRAKESBORO SEMORA CRYSTAL RIVER State AR WA LA TX FL VA MT TN TX TN LA IA IL PA VA MO OH NC WY AL LA SC FL SD FL UT VA AL UT WA MS NY AZ FL OR MO NY TX NY KS MA MD LA LA GA OH KY NC FL Total Air and Water Emissions (grams) 4.16 4.16 4.13 4.09 4.08 4.04 4.00 3.95 3.92 3.92 3.85 3.83 3.81 3.63 3.63 3.61 3.60 3.58 3.58 3.57 3.57 3.54 3.50 3.48 3.40 3.40 3.39 3.35 3.26 3.26 3.26 3.23 3.23 3.22 3.21 3.20 3.20 3.20 3.19 3.18 3.18 3.15 3.14 3.13 3.11 3.09 3.08 3.08 3.05 50 Appendix R. 100 U.S. Counties Reporting the Most Air and Water Releases of Dioxins, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 County BRAZORIA IBERVILLE HARRIS COOS BIBB SEDGWICK LITTLE RIVER CALCASIEU ESCAMBIA GRENADA MIDDLESEX ST CHARLES EAST BATON ROUGE PORTER MARSHALL LAKE DORCHESTER BEXAR SANGAMON SCHUYLKILL JEFFERSON SULLIVAN DUVAL LA CROSSE JEFFERSON ASHLEY NORTHWEST ARCTIC MONROE HUMPHREYS NORTHAMPTON MOBILE STONE SUFFOLK SAN BERNARDINO GRUNDY COLLIN YORK YORK PUTNAM APACHE CLARK CHOCTAW FREDERICK BEAVER LEE IRON TRUMBULL NEZ PERCE UNION ATASCOSA PIKE State TX LA TX NH AL KS AR LA AL MS NJ LA LA IN WV IN SC TX IL PA AR TN FL WI AL AR AK NY TN PA AL MS NY CA IL TX PA VA FL AZ NV AL MD PA IL MO OH ID AR TX AL Total Air and Water Emissions (grams) 525.87 301.64 254.91 151.86 74.97 57.51 47.93 43.33 39.12 37.22 26.21 23.81 22.58 17.80 16.63 16.51 11.46 10.29 8.99 8.73 8.70 8.24 8.21 8.07 7.91 7.67 7.53 7.33 7.18 6.99 6.87 6.56 6.20 5.89 5.85 5.82 5.62 5.59 5.52 5.39 5.31 5.20 5.19 5.14 5.11 5.00 4.80 4.78 4.77 4.67 4.63 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 94 96 97 98 99 100 County MARTIN RICHMOND BRISTOL JASPER BERKELEY PERSON KING CASS MANATEE NEW CASTLE BUCKINGHAM ROSEBUD QUEENS STEWART SHEBOYGAN JEFFERSON ASCENSION MERCER INDIANA RAPIDES CHATHAM RANDOLPH PIKE PIMA ISLE OF WIGHT DEFIANCE FORSYTH PLATTE WILCOX GEORGETOWN ORANGE PENNINGTON NIAGARA ORANGE PASCO UINTAH BALTIMORE BOTETOURT LOS ANGELES HONOLULU WILL MUHLENBERG TOOELE COWLITZ DE SOTO KEMPER HENDERSON BROWARD MORROW State FL GA MA MO SC NC WA TX FL DE VA MT NY TN WI OH LA ND PA LA GA IL MO AZ VA OH NC WY AL SC FL SD NY NY FL UT MD VA CA HI IL KY UT WA LA MS KY FL OR Total Air and Water Emissions (grams) 4.57 4.47 4.44 4.29 4.28 4.24 4.16 4.09 4.08 4.07 4.04 4.00 3.97 3.92 3.88 3.87 3.85 3.83 3.82 3.82 3.82 3.81 3.80 3.76 3.63 3.60 3.58 3.58 3.57 3.54 3.50 3.48 3.46 3.41 3.40 3.40 3.39 3.39 3.31 3.30 3.29 3.29 3.26 3.26 3.26 3.26 3.22 3.22 3.21 51 Appendix S. Land Releases of Recognized Carcinogens, Developmental Toxicants, and Reproductive Toxicants, 2004: By State Rank State 1 NV 2 AK 3 UT 4 MO 5 MT 6 TN 7 ID 8 AZ 9 AL 10 CA 11 OH 12 OR 13 CO 14 IN 15 TX 16 FL 17 WA 18 KY 19 PA 20 LA 21 IL 22 WV 23 NC 24 GA 25 NY 26 SD Total On-Site Land Releases (pounds) 217,684,550 146,041,919 71,046,244 29,112,845 19,213,010 13,096,523 11,561,621 9,051,038 8,143,122 8,055,481 7,218,389 7,178,954 6,807,014 5,429,586 4,897,645 4,660,221 4,139,934 3,879,206 3,850,831 3,270,052 3,061,609 2,967,047 2,836,439 2,623,216 1,650,634 1,521,688 Rank 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 National State VA MI MS NM OK AR WY SC ND MD MN KS DE NJ NE HI WI IA MA ME NH CT RI DC VT Total On-Site Land Releases (pounds) 1,211,016 1,130,688 1,089,421 977,681 955,042 821,229 521,310 485,847 465,890 365,227 321,863 304,377 222,770 176,761 151,277 125,694 114,161 82,047 58,794 10,684 3,446 870 250 0 0 608,595,163 52 Appendix T. 100 U.S. Zip Codes Reporting the Most Land Releases of Recognized Carcinogens, Developmental Toxicants, and Reproductive Toxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 Zip Code 99752 89419 84006 89414 89803 89438 89822 63629 65440 84044 59638 59701 99801 37040 89003 97812 83624 93239 35459 80860 80468 84022 43616 99153 37134 32831 89801 99712 84029 83846 85532 93206 36079 61615 70665 85614 83276 47670 57754 63048 85629 85235 15698 14107 63638 16003 45144 28429 45620 89821 86321 City KOTZEBUE LOVELOCK BINGHAM CANYON/COPPERTON GOLCONDA/MIDAS ELKO VALMY CARLIN BUNKER BOSS MAGNA JEFFERSON CITY BUTTE JUNEAU CLARKSVILLE BEATTY ARLINGTON GRAND VIEW KETTLEMAN CITY EMELLE VICTOR PARSHALL DUGWAY/CLIVE OREGON METALINE FALLS NEW JOHNSONVILLE ORLANDO ELKO FAIRBANKS GRANTSVILLE/ROWLEY MULLAN CLAYPOOL BUTTONWILLOW TROY PEORIA CARLYSS/SULPHUR GREEN VALLEY SODA SPRINGS PRINCETON LEAD HERCULANEUM SAHUARITA HAYDEN YUKON MODEL CITY ELLINGTON BUTLER MANCHESTER CASTLE HAYNE CHESHIRE CRESCENT VALLEY BAGDAD State AK NV UT NV NV NV NV MO MO UT MT MT AK TN NV OR ID CA AL CO CO UT OH WA TN FL NV AK UT ID AZ CA AL IL LA AZ ID IN SD MO AZ AZ PA NY MO PA OH NC OH NV AZ Total OnSite Land Releases (pounds) 135,329,476 85,322,626 53,818,352 42,382,733 35,016,558 23,485,855 18,790,206 13,358,616 12,435,901 11,398,156 9,239,419 8,940,004 8,431,523 8,010,194 7,845,810 7,158,025 6,534,179 5,860,697 3,622,389 3,455,674 3,021,010 2,848,464 2,673,566 2,633,893 2,477,968 2,463,302 2,432,118 2,239,090 2,217,774 2,215,061 2,164,735 1,922,463 1,917,766 1,891,630 1,876,552 1,754,066 1,537,100 1,478,806 1,468,405 1,468,275 1,436,461 1,392,809 1,362,057 1,256,700 1,239,617 1,049,897 1,011,109 996,042 947,032 919,863 910,927 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 Zip Code 85237 32226 39746 99352 73860 45750 78380 42337 35186 37662 83873 89045 41045 89418 30170 71901 35580 83227 32177 98531 26739 37050 70765 25265 78359 26366 47882 27343 26041 43913 47928 87416 47885 38401 31061 42452 48161 35772 46402 77536 26574 47601 59759 75691 40272 47629 88043 30263 62201 City KEARNY JACKSONVILLE HAMILTON RICHLAND WAYNOKA MARIETTA ROBSTOWN DRAKESBORO WILSONVILLE KINGSPORT WALLACE ROUND MOUNTAIN GHENT IMLAY ROOPVILLE HOT SPRINGS PARRISH CLAYTON PALATKA CENTRALIA MOUNT STORM CUMBERLAND CITY PLAQUEMINE NEW HAVEN GREGORY HAYWOOD SULLIVAN SEMORA MOUNDSVILLE BRILLIANT CAYUGA FRUITLAND WEST TERRE HAUTE COLUMBIA MILLEDGEVILLE ROBARDS/HENDERSON MONROE STEVENSON GARY DEER PARK GRANT TOWN BOONVILLE WHITEHALL TATUM LOUISVILLE NEWBURGH HURLEY NEWNAN E.SAINT LOUIS/SAUGET State AZ FL MS WA OK OH TX KY AL TN ID NV KY NV GA AR AL ID FL WA WV TN LA WV TX WV IN NC WV OH IN NM IN TN GA KY MI AL IN TX WV IN MT TX KY IN NM GA IL Total OnSite Land Releases (pounds) 880,157 871,132 866,816 851,786 794,539 747,430 722,090 710,120 700,296 668,556 655,826 609,959 608,579 606,830 600,552 570,394 557,605 554,423 542,602 530,654 530,522 521,870 490,419 483,418 481,067 465,868 462,895 442,704 439,616 413,402 387,146 383,254 379,864 379,774 375,332 362,589 359,320 354,548 344,033 342,263 336,518 335,346 334,900 332,797 332,642 331,642 321,299 320,219 318,614 53 Appendix U. 100 U.S. Counties Reporting the Most Land Releases of Recognized Carcinogens, Developmental Toxicants, and Reproductive Toxicants, 2004 Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 County NORTHWEST ARCTIC PERSHING HUMBOLDT SALT LAKE ELKO EUREKA REYNOLDS IRON JEFFERSON SILVER BOW NYE JUNEAU MONTGOMERY GILLIAM OWYHEE KINGS TOOELE SUMTER GILA TELLER PIMA GRAND SHOSHONE LUCAS PEND OREILLE HUMPHREYS ORANGE FAIRBANKS NORTH STAR PEORIA KERN PIKE CALCASIEU CARIBOU JEFFERSON GIBSON LAWRENCE NIAGARA WESTMORELAND NEW HANOVER BUTLER WASHINGTON ADAMS GALLIA LANDER YAVAPAI PINAL WHITE PINE DUVAL MONROE BENTON SULLIVAN State AK NV NV UT NV NV MO MO MT MT NV AK TN OR ID CA UT AL AZ CO AZ CO ID OH WA TN FL AK IL CA AL LA ID MO IN SD NY PA NC PA OH OH OH NV AZ AZ NV FL MS WA TN Total OnSite Land Releases (pounds) 135,329,476 85,929,456 65,757,170 65,216,816 36,696,303 18,790,206 14,598,233 12,435,901 9,574,327 8,940,004 8,463,426 8,431,523 8,010,194 7,158,025 6,534,179 5,860,697 5,064,954 3,623,093 3,557,544 3,455,674 3,190,862 3,021,010 2,873,920 2,673,566 2,633,893 2,479,712 2,463,302 2,258,538 2,034,692 1,923,322 1,917,766 1,877,303 1,537,100 1,516,716 1,478,806 1,468,405 1,447,084 1,362,200 1,100,143 1,049,897 1,031,683 1,011,109 947,032 930,452 923,865 880,157 877,311 871,259 866,816 851,786 846,531 Rank 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 County MAJOR NUECES SHELBY MUHLENBERG WARRICK CARROLL PERSON HEARD GARLAND WALKER CUSTER PUTNAM LEWIS GRANT STEWART JEFFERSON IBERVILLE INDIANA MASON SAN PATRICIO HARRISON SULLIVAN SAN JUAN MARSHALL JEFFERSON HARRIS MONROE MAURY JEFFERSON VERMILLION VIGO PUTNAM CLERMONT HENDERSON JACKSON LAKE GRANT MARION RUSK COWETA ST CLAIR LIMESTONE ANDREWS ROANE BALTIMORE COSHOCTON TITUS BARTOW HALIFAX State OK TX AL KY IN KY NC GA AR AL ID FL WA WV TN KY LA PA WV TX WV IN NM WV OH TX MI TN AL IN IN GA OH KY AL IN NM WV TX GA IL TX TX TN MD OH TX GA VA Total OnSite Land Releases (pounds) 794,539 749,153 722,510 721,250 666,988 608,579 604,780 600,552 570,950 557,605 554,423 543,376 530,654 530,522 521,870 509,905 490,780 486,266 483,418 481,067 465,868 462,895 461,412 440,702 413,402 402,603 399,290 389,463 389,271 387,162 385,646 375,332 370,630 362,589 354,548 347,466 340,529 337,919 332,797 320,219 320,119 317,683 312,782 310,595 306,584 302,159 300,481 299,087 297,582 54 Appendix V. Substances Reported to TRI in 2004 with Known or Suspected Health Effects R= Recognized S= Suspected These substances may pose other health threats, such as damage to the endocrine or cardiovascular systems. In addition, some of the chemicals not noted as recognized carcinogens, for example, may be suspected carcinogens. Refer to the methodology for details about how we compiled the list of health effects. Chemical Name 1,1,1,2-TETRACHLOROETHANE 1,1,1-TRICHLOROETHANE 1,1,2,2-TETRACHLOROETHANE 1,1,2-TRICHLOROETHANE 1,1-DICHLORO-1-FLUOROETHANE 1,1-DIMETHYL HYDRAZINE 1,2,3-TRICHLOROPROPANE 1,2,4-TRICHLOROBENZENE 1,2,4-TRIMETHYLBENZENE 1,2-BUTYLENE OXIDE 1,2-DIBROMO-3-CHLOROPROPANE 1,2-DIBROMOETHANE 1,2-DICHLOROBENZENE 1,2-DICHLOROETHANE 1,2-DICHLOROETHYLENE 1,2-DICHLOROPROPANE 1,2-DIPHENYLHYDRAZINE 1,2-PHENYLENEDIAMINE 1,3-BUTADIENE 1,3-DICHLOROBENZENE 1,3-DICHLOROPROPYLENE 1,4-DICHLORO-2-BUTENE 1,4-DICHLOROBENZENE 1,4-DIOXANE 2,4,5-TRICHLOROPHENOL 2,4,6-TRICHLOROPHENOL 2,4-D 2,4-D 2-ETHYL-4-METHYLPENTYL ESTER 2,4-D 2-ETHYLHEXYL ESTER 2,4-D BUTOXYETHYL ESTER 2,4-D BUTYL ESTER 2,4-D ISOPROPYL ESTER 2,4-D SODIUM SALT 2,4-DB 2,4-DIAMINOANISOLE 2,4-DIAMINOANISOLE SULFATE 2,4-DIAMINOTOLUENE 2,4-DIMETHYLPHENOL 2,4-DINITROPHENOL 2,4-DINITROTOLUENE 2,4-DITHIOBIURET 2,4-DP 2,6-DINITROTOLUENE 2,6-XYLIDINE 2-ACETYLAMINOFLUORENE 2-CHLOROACETOPHENONE 2-ETHOXYETHANOL 2-MERCAPTOBENZOTHIAZOLE 2-METHOXYETHANOL 2-METHYLLACTONITRILE 2-METHYLPYRIDINE 2-NITROPHENOL Carcinogen Developmental Toxicant Reproductive Toxicant R R R R R R R R R R R R R R R R R R R R Neurotoxicant S S S S S S S S S S S S S S S S S S S S R S S S S S S S Respiratory Toxicant S S S S S S S S S S S S S S S S S S S R R R R S R R R R R R R R R R S S S S S S S S S S S S S S S S S S 55 Chemical Name 2-NITROPROPANE 2-PHENYLPHENOL 3,3'-DICHLOROBENZIDINE 3,3'-DICHLOROBENZIDINE DIHYDROCHLORIDE 3,3'-DIMETHOXYBENZIDINE 3,3'-DIMETHOXYBENZIDINE DIHYDROCHLORIDE 3,3'-DIMETHYLBENZIDINE 3-CHLORO-2-METHYL-1-PROPENE 3-CHLOROPROPIONITRILE 3-IODO-2-PROPYNYL BUTYLCARBAMATE 4,4'-DIAMINODIPHENYL ETHER 4,4'-ISOPROPYLIDENEDIPHENOL 4,4'-METHYLENEBIS(2-CHLOROANILINE) 4,4'-METHYLENEBIS(N,N-DIMETHYL)BENZENAMINE 4,4'-METHYLENEDIANILINE 4,6-DINITRO-O-CRESOL 4-AMINOAZOBENZENE 4-AMINOBIPHENYL 4-DIMETHYLAMINOAZOBENZENE 4-NITROPHENOL ACEPHATE ACETALDEHYDE ACETAMIDE ACETONE ACETONITRILE ACIFLUORFEN, SODIUM SALT ACROLEIN ACRYLAMIDE ACRYLIC ACID ACRYLONITRILE ALACHLOR ALDICARB ALDRIN ALLYL ALCOHOL ALLYL CHLORIDE ALLYLAMINE ALPHA-NAPHTHYLAMINE ALUMINUM (FUME OR DUST) ALUMINUM OXIDE (FIBROUS FORMS) ALUMINUM PHOSPHIDE AMETRYN AMITRAZ AMITROLE AMMONIA AMMONIUM SULFATE (SOLUTION) ANILINE ANTIMONY ANTIMONY COMPOUNDS ARSENIC ARSENIC COMPOUNDS ASBESTOS (FRIABLE) ATRAZINE BARIUM BENDIOCARB BENOMYL BENZAL CHLORIDE BENZENE BENZIDINE BENZOIC TRICHLORIDE BENZOYL CHLORIDE BENZYL CHLORIDE BERYLLIUM BERYLLIUM COMPOUNDS Carcinogen R R R R R R R R Developmental Toxicant Reproductive Toxicant Neurotoxicant S S S Respiratory Toxicant S S S S S S R R R R R R R R R S S S S S S S S S S S S S S S S S S S R R R R S S S S S R S S S S S S R R S S S S S S S S S S S S S S S S S S S R R R R R R R R R R R R R S S R R R R S S S S S S S S S S S S S S S S S 56 Chemical Name BETA-NAPHTHYLAMINE BIFENTHRIN BIPHENYL BIS(2-CHLORO-1-METHYLETHYL) ETHER BIS(2-CHLOROETHYL) ETHER BIS(CHLOROMETHYL) ETHER BIS(TRIBUTYLTIN) OXIDE BORON TRIFLUORIDE BROMINE BROMOCHLORODIFLUOROMETHANE BROMOFORM BROMOMETHANE BROMOTRIFLUOROMETHANE BROMOXYNIL BROMOXYNIL OCTANOATE BUTYL ACRYLATE BUTYL BENZYL PHTHALATE BUTYRALDEHYDE C.I. ACID RED 114 C.I. DIRECT BLUE 218 C.I. FOOD RED 15 C.I. SOLVENT YELLOW 14 C.I. SOLVENT YELLOW 3 C.I. SOLVENT YELLOW 34 CADMIUM CADMIUM COMPOUNDS CALCIUM CYANAMIDE CAPTAN CARBARYL CARBOFURAN CARBON DISULFIDE CARBON TETRACHLORIDE CARBONYL SULFIDE CARBOXIN CATECHOL CERTAIN GLYCOL ETHERS CHLORDANE CHLORENDIC ACID CHLORINE CHLORINE DIOXIDE CHLOROACETIC ACID CHLOROBENZENE CHLOROBENZILATE CHLORODIFLUOROMETHANE CHLOROETHANE CHLOROFORM CHLOROMETHANE CHLOROMETHYL METHYL ETHER CHLOROPICRIN CHLOROPRENE CHLOROTHALONIL CHLORPYRIFOS METHYL CHLORSULFURON CHROMIUM CHROMIUM COMPOUNDS COBALT COBALT COMPOUNDS COPPER COPPER COMPOUNDS CREOSOTE CRESOL (MIXED ISOMERS) CROTONALDEHYDE CUMENE Carcinogen R Developmental Toxicant Reproductive Toxicant Neurotoxicant S S S S R R R S S S S S S S R R Respiratory Toxicant S S S S S S S S R R S R S S R R R R R R R R R R R R R R R R R R R S S S S S S S S S S S S S S S S S S S S S S S S R S S S S R R R R S S S S R R R R R R R R S S S S S S S R S S S S S S S S S S S S 57 Chemical Name CUMENE HYDROPEROXIDE CUPFERRON CYANAZINE CYANIDE COMPOUNDS CYCLOATE CYCLOHEXANE CYCLOHEXANOL CYFLUTHRIN CYHALOTHRIN DAZOMET DESMEDIPHAM DI(2-ETHYLHEXYL) PHTHALATE DIAMINOTOLUENE (MIXED ISOMERS) DIAZINON DIBUTYL PHTHALATE DICHLOROBROMOMETHANE DICHLORODIFLUOROMETHANE DICHLOROFLUOROMETHANE DICHLOROMETHANE DICHLOROTETRAFLUOROETHANE (CFC-114) DICHLORVOS DICOFOL DICYCLOPENTADIENE DIEPOXYBUTANE DIETHANOLAMINE DIETHYL PHTHALATE DIETHYL SULFATE DIGLYCIDYL RESORCINOL ETHER DIHYDROSAFROLE DIISOCYANATES DIMETHOATE DIMETHYL PHTHALATE DIMETHYL SULFATE DIMETHYLAMINE DIMETHYLCARBAMYL CHLORIDE DINITROBUTYL PHENOL DINITROTOLUENE (MIXED ISOMERS) DINOCAP DIPHENYLAMINE DIPROPYL ISOCINCHOMERONATE DISODIUM CYANODITHIOIMIDOCARBONATE DIURON EPICHLOROHYDRIN ETHOPROP ETHYL ACRYLATE ETHYL CHLOROFORMATE ETHYL DIPROPYLTHIOCARBAMATE ETHYLBENZENE ETHYLENE ETHYLENE GLYCOL ETHYLENE OXIDE ETHYLENE THIOUREA ETHYLENEIMINE ETHYLIDENE DICHLORIDE FAMPHUR FENOXYCARB FENPROPATHRIN FENTHION FERBAM FLUAZIFOP BUTYL FLUORINE FLUOROURACIL FLUVALINATE Carcinogen Developmental Toxicant Reproductive Toxicant Neurotoxicant Respiratory Toxicant S R R S S S S S S S S S R R R R R R R R R R S S S S S S S S S S S S S R S S R R R S S S S S S S S S S S S R R R R R R S S R S S S S S S S S S S S R R R R R R R R R R R R R R S S S S S S S S S S S S S S S R S S S S R S S S S R S R R S 58 Chemical Name FOLPET FORMALDEHYDE FORMIC ACID FREON 113 HEPTACHLOR HEXACHLORO-1,3-BUTADIENE HEXACHLOROBENZENE HEXACHLOROCYCLOPENTADIENE HEXACHLOROETHANE HEXACHLOROPHENE HEXAMETHYLPHOSPHORAMIDE HYDRAMETHYLNON HYDRAZINE HYDRAZINE SULFATE HYDROCHLORIC ACID AEROSOLS HYDROGEN CYANIDE HYDROGEN FLUORIDE HYDROQUINONE IRON PENTACARBONYL ISOBUTYRALDEHYDE ISOPROPYL ALCOHOL LACTOFEN LEAD LEAD COMPOUNDS LINDANE LINURON LITHIUM CARBONATE MALATHION MALEIC ANHYDRIDE MALONONITRILE MANEB MANGANESE MANGANESE COMPOUNDS M-CRESOL M-DINITROBENZENE MERCURY MERCURY COMPOUNDS MERPHOS METHACRYLONITRILE METHAM SODIUM METHANOL METHIOCARB METHOXONE METHOXONE SODIUM SALT METHOXYCHLOR METHYL ACRYLATE METHYL CHLOROCARBONATE METHYL ETHYL KETONE METHYL HYDRAZINE METHYL IODIDE METHYL ISOBUTYL KETONE METHYL ISOCYANATE METHYL ISOTHIOCYANATE METHYL METHACRYLATE METHYL PARATHION METHYL TERT-BUTYL ETHER METHYLENE BROMIDE METHYLENEBIS(PHENYLISOCYANATE) MEVINPHOS MICHLER'S KETONE MOLINATE MOLYBDENUM TRIOXIDE MONOCHLOROPENTAFLUOROETHANE Carcinogen R R Developmental Toxicant R R R R Reproductive Toxicant R R R R R R R Neurotoxicant S S S S S S S S S S S S S S S S S R R R R R R R R R R S S R R R R R S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S R S S S S S S R R Respiratory Toxicant S S S S S S S S S S S S S S S S S S S S S S S S R S S S S 59 Chemical Name M-XYLENE MYCLOBUTANIL N,N-DIMETHYLANILINE N,N-DIMETHYLFORMAMIDE NABAM NALED NAPHTHALENE N-BUTYL ALCOHOL N-HEXANE NICKEL NICKEL COMPOUNDS NICOTINE AND SALTS NITRAPYRIN NITRIC ACID NITRILOTRIACETIC ACID NITROBENZENE NITROFEN NITROGEN MUSTARD NITROGLYCERIN N-METHYL-2-PYRROLIDONE N-METHYLOLACRYLAMIDE N-NITROSODIETHYLAMINE N-NITROSODIMETHYLAMINE N-NITROSODI-N-BUTYLAMINE N-NITROSODI-N-PROPYLAMINE N-NITROSODIPHENYLAMINE N-NITROSOMETHYLVINYLAMINE N-NITROSO-N-ETHYLUREA N-NITROSO-N-METHYLUREA N-NITROSOPIPERIDINE O-ANISIDINE O-CRESOL O-DINITROBENZENE OSMIUM TETROXIDE O-TOLUIDINE O-TOLUIDINE HYDROCHLORIDE OXYDEMETON METHYL OXYDIAZON O-XYLENE OZONE PARALDEHYDE PARAQUAT DICHLORIDE PARATHION P-CHLOROANILINE P-CRESIDINE P-CRESOL P-DINITROBENZENE PEBULATE PENTACHLOROBENZENE PENTACHLOROETHANE PENTACHLOROPHENOL PENTOBARBITAL SODIUM PERCHLOROMETHYL MERCAPTAN PERMETHRIN PHENANTHRENE PHENOL PHENOTHRIN PHENYTOIN PHOSGENE PHOSPHINE PHOSPHORIC ACID PHOSPHORUS (YELLOW OR WHITE) PHTHALIC ANHYDRIDE Carcinogen Developmental Toxicant Reproductive Toxicant R R Neurotoxicant S Respiratory Toxicant S S S S R S S S S S R R R R R R S S S S S S S S R R R R S S S S S S R R R R R R R R R R R R R S S S S S S S S R R R S S S S R R S S S S S S R S S S S S S S S S R R R R R S S S S S S S S S S S R R S S S S S S S S S S S S S S S 60 Chemical Name PICRIC ACID PIPERONYL BUTOXIDE PIRIMIPHOS METHYL P-NITROANILINE P-NITROSODIPHENYLAMINE POLYBROMINATED BIPHENYLS POLYCHLORINATED BIPHENYLS POLYCYCLIC AROMATIC COMPOUNDS POTASSIUM BROMATE POTASSIUM DIMETHYLDITHIOCARBAMATE P-PHENYLENEDIAMINE PROFENOFOS PROMETRYN PRONAMIDE PROPACHLOR PROPANE SULTONE PROPANIL PROPARGITE PROPARGYL ALCOHOL PROPETAMPHOS PROPIONALDEHYDE PROPOXUR PROPYLENE PROPYLENE OXIDE PROPYLENEIMINE P-XYLENE PYRIDINE QUINOLINE QUINONE QUIZALOFOP-ETHYL RESMETHRIN S,S,S-TRIBUTYLTRITHIOPHOSPHATE SAFROLE SEC-BUTYL ALCOHOL SELENIUM SELENIUM COMPOUNDS SIMAZINE SODIUM AZIDE SODIUM DIMETHYLDITHIOCARBAMATE SODIUM FLUOROACETATE SODIUM HYDROXIDE (SOLUTION) SODIUM NITRITE SODIUM O-PHENYLPHENOXIDE STRYCHNINE AND SALTS STYRENE STYRENE OXIDE SULFURIC ACID AEROSOLS SULFURYL FLUORIDE TEBUTHIURON TEMEPHOS TEREPHTHALIC ACID TERT-BUTYL ALCOHOL TETRACHLOROETHYLENE TETRACHLORVINPHOS TETRACYCLINE HYDROCHLORIDE TETRAMETHRIN THALLIUM THIABENDAZOLE THIOACETAMIDE THIOBENCARB THIODICARB THIOPHANATE-METHYL THIOUREA Carcinogen R R R R R Developmental Toxicant Reproductive Toxicant Respiratory Toxicant R R S S R S S S S S S S S S S S R R R R Neurotoxicant S S S S S S S R S S S S R R R S S S S S S R R S S S S S S R R R R R S S S S S S S S S S S S S S S S S S R S S R S S S S S S S R S S S S S R S S S R R R S S S R 61 Chemical Name THIRAM THORIUM DIOXIDE TITANIUM TETRACHLORIDE TOLUENE TOLUENE DIISOCYANATE (MIXED ISOMERS) TOLUENE-2,4-DIISOCYANATE TOLUENE-2,6-DIISOCYANATE TOXAPHENE TRANS-1,3-DICHLOROPROPENE TRANS-1,4-DICHLORO-2-BUTENE TRIADIMEFON TRIALLATE TRIBUTYLTIN METHACRYLATE TRICHLORFON TRICHLOROETHYLENE TRICHLOROFLUOROMETHANE TRIETHYLAMINE TRIFORINE TRIPHENYLTIN HYDROXIDE TRIS(2,3-DIBROMOPROPYL) PHOSPHATE TRYPAN BLUE URETHANE VANADIUM VINCLOZOLIN VINYL ACETATE VINYL BROMIDE VINYL CHLORIDE VINYLIDENE CHLORIDE WARFARIN AND SALTS XYLENE (MIXED ISOMERS) ZINC (FUME OR DUST) ZINC COMPOUNDS ZINEB Carcinogen Developmental Toxicant Reproductive Toxicant Neurotoxicant S Respiratory Toxicant S R R R R R R R R R R R R R R R R S S S S S S S S S S S S S S S S S S S S R R R S R S S R R R R S S S S S S S S S S S S S 62 END NOTES H.R. Conf. Rep. No. 962, 99th Cong., 2dSESS. (1986), “Joint explanatory statement of the Committee of Conference.” 2 U.S. Environmental Protection Agency, Toxics Release Inventory Program, “What is the Toxics Release Inventory (TRI) Program?”, accessed January 29, 2007 at http://www.epa.gov/tri/whatis.htm. 3 U.S. Environmental Protection Agency, Office of Pollution Prevention and Toxics, Chemical Hazard Data Availability Study, April 1998. 4 U.S. Environmental Protection Agency, Toxics Release Inventory, calculated using the TRI Explorer at http://www.epa.gov/triexplorer/ on January 24, 2007. This total includes releases in the 50 U.S. states only. 5 American Cancer Society, Cancer Facts & Figures 2006, 1. Accessed January 10, 2007 at http://www.cancer.org/downloads/STT/CAFF2006PWSecured.pdf. 6 American Cancer Society, Cancer Facts & Figures 2006, 22. Accessed January 10, 2007 at http://www.cancer.org/downloads/STT/CAFF2006PWSecured.pdf. 7 American Cancer Society, Cancer Facts & Figures 2006, 23. Accessed January 24, 2007 at http://www.cancer.org/downloads/STT/CAFF2006PWSecured.pdf. 8 American Cancer Society, Cancer Facts & Figures 2006, 24. Accessed January 24, 2007 at http://www.cancer.org/downloads/STT/CAFF2006PWSecured.pdf. 9 U.S. Department of Health and Human Services, Public Health Service, National Toxicology Program, Report on Carcinogens, Eleventh Edition, January 2005. Substance Profiles, Acetaldehyde, accessed January 11, 2007 at http://ntp.niehs.nih.gov/ntp/roc/eleventh/profiles/s001acet.pdf. 10 U.S. Department of Health and Human Services, Public Health Service, National Toxicology Program, Report on Carcinogens, Eleventh Edition, January 2005. Substance Profiles, Acetaldehyde, accessed January 11, 2007 at http://ntp.niehs.nih.gov/ntp/roc/eleventh/profiles/s001acet.pdf. 11 U.S. Environmental Protection Agency, Office of Pollution Prevention and Toxics, Chemical Hazard Data Availability Study, April 1998, as detailed in Table 1 of Appendix III. 12 U.S. Agency for Toxic Substances and Disease Registry, ToxFAQs for Toluene, February 2001. 13 U.S. Agency for Toxic Substances and Disease Registry, ToxFAQs for Carbon Disulfide, September 1997. 14 Lead compounds are not specifically identified as developmental or reproductive toxicants under Proposition 65. Environmental Defense, however, classifies lead compounds as “recognized” developmental and reproductive toxicants on its Scorecard.org website. The TOXNET database of the National Library of Medicine cites several studies suggesting that exposure to inorganic lead compounds can lead to reproductive problems and impaired neurological development in children. As a result, we include lead compounds as recognized developmental and reproductive toxicants for purposes of this study. We made a similar determination for cadmium compounds, even though Proposition 65 lists only elemental cadmium as a developmental and reproductive toxicant. 15 Environmental Defense, Scorecard, “Health Effects: Suspected Neurotoxicants,” accessed February 7, 2007 at http://www.scorecard.org/health-effects/. 16 Environmental Defense, Scorecard, “Health Effects: Suspected Neurotoxicants,” accessed February 7, 2007 at http://www.scorecard.org/health-effects/. 17 California Environmental Protection Agency, Air Resources Board, Toxic Air Contaminant Identification List Summaries: Methanol, September 1997. 18 U.S. Department of Labor, Occupational Safety & Health Administration, SIC Division Structure, “Description for 2873: Nitrogenous Fertilizers,” accessed January 30, 2007 at http://www.osha.gov/pls/imis/sic_manual.html. 19 Edison Electric Institute, “Straight Answers about the Toxics Release Inventory: FAQ about Hydrogen Fluoride,” April 2006; Electric Power Research Institute, “Toxics Release Inventory Chemical Profile: Hydrogen Fluoride,” December 1998. 20 Rob McConnell et al, “Asthma in Exercising Children Exposed to Ozone: A Cohort Study,” The Lancet, 2 February 2002. 21 Environmental Defense, Scorecard, “Health Effects: Suspected Respiratory Toxicants,” accessed February 7, 2007 at http://www.scorecard.org/health-effects/. 22 U.S. Agency for Toxic Substances and Disease Registry, “Medical Management Guidelines for Hydrogen Chloride,” accessed January 30, 2007 at http://www.atsdr.cdc.gov/MHMI/mmg173.html. 23 U.S. Environmental Protection Agency, Technology Transfer Network, Air Toxics Website, Hydrochloric Acid (Hydrogen Chloride) Hazard Summary, revised in January 2000. Accessed January 30, 2007 at http://www.epa.gov/ttn/atw/hlthef/hydrochl.html. 24 Electric Power Research Institute, “Toxics Release Inventory Chemical Profile: Hydrogen Chloride,” December 1998. 1 63 U.S. Environmental Protection Agency, NAS Review Draft of Exposure and Human Health Reassessment of 2,3,7,8Tetrachlorodibenzo-p-Dioxin (TCDD) and Related Compounds, October 2004. See also EPA, Information Sheet 1, “Dioxin: Summary of the Dioxin Reassessment Science,” updated October 2004, accessed January 11, 2007 at http://oaspub.epa.gov/eims/eimscomm.getfile?p_download_id=435879. 26 U.S. Agency for Toxic Substances and Disease Registry, Case Studies in Environmental Medicine: Lead Toxicity, October 2000; American Academy of Pediatrics, “Lead Exposure in Children: Prevention, Detection and Management,” Pediatrics, 1036-1048 (October 2005). 27 Lead compounds are not specifically identified as developmental or reproductive toxicants under Proposition 65. Environmental Defense, however, classifies lead compounds as “recognized” developmental and reproductive toxicants on its Scorecard.org website. The TOXNET database of the National Library of Medicine cites several studies suggesting that exposure to inorganic lead compounds can lead to reproductive problems and impaired neurological development in children. As a result, we include lead compounds as recognized developmental and reproductive toxicants for purposes of this study. We made a similar determination for cadmium compounds, even though Proposition 65 lists only elemental cadmium as a developmental and reproductive toxicant. 28 40 C.F.R. § 372.65; EPA EPCRA 313 Chemical list for Reporting Year 2004, accessed March 5, 2007 at http://www.epa.gov/tri/chemical/RY2004ChemicalLists.pdf. 29 For Form R reporting requirements see 40 C.F.R. § 372.85 30 For Form A reporting requirements see 40 C.F.R. § 372.95 31 71 Fed. Reg. 76,932, 76,934 (Dec. 22, 2006) 32 40 C.F.R. § 372.27 (establishing Form A eligibility if facility does not exceed threshold level of 500 pounds of total quantities of a toxic released, disposed, treated, recycled or combusted at the facility, and amounts transferred from the facility to offsite locations for treatment, disposal, recycling or combustion), amended by 71 Fed. Reg. 76,944 (Dec. 22, 2006)(expanding Form A eligibility from 500 pound total quantity threshold to 5,000 pounds if total onsite releases and disposal do not exceed 2,000 pounds) 33 71 Fed. Reg. 76,932 et seq. (Dec. 22, 2006) (Toxics Release Inventory Burden Reduction Final Rule) 34 71 Fed. Reg. 76,935 35 64 Fed. Reg. 58,732 (Oct. 29, 1999); 40 C.F.R. § 372.28 (exempting persistent bioaccumulative toxins from alternative threshold certification) 36 71 Fed. Reg. 76,963 37 Statement of John B. Stephenson, EPA Actions Could Reduce Availability of Environmental Information to the Public, GAO-07-464T, February 2007. 38 Toxics Use Reduction Institute, Results to Date, accessed February 19, 2007 at http://turadata.turi.org/Success/ResultsToDate.html. 39 A complete list of sources and methodologies on which Environmental Defense’s listings are based can be found at http://www.scorecard.org/health-effects/. 40 U.S. Department of Labor, Occupational Safety & Health Administration, “SIC Division Structure,” accessed February 12, 2007 at http://www.osha.gov/pls/imis/sic_manual.html. 25 64